How Do Electrons Form a Bond in Covalent Bonding Despite Their Mutual Repulsion?

In summary, the concept of opposite charges attracting and like charges repelling is seen in chemical bonding, particularly in covalent bonding where electrons form a bond and are attracted to both positively charged nuclei while being repelled by each other. This results in a local equilibrium where the atoms are held at a specific distance from each other. The interaction between electrons and nuclei is not solely based on electric attraction, but also on the instantaneous dipole. The reason for bond formation is related to quantum mechanics and the uncertainty principle, where electrons can occupy more space and have lower kinetic energy when bonded to multiple atoms.
  • #1
bronx
4
0
There's a rule bout unlike charges attract and like charges repel one another. How is it that in chemical bonding like in covalent bonding electrons form a bond or there is attraction from one unto the other. Isn't that ironic?
 
Chemistry news on Phys.org
  • #2
Well, to take the simplest example of the bond in a hydrogen molecule, you have two positively charged nuclei, and two electrons. Each electron is attracted to both nuclei, but repelled by the other electron. Chemical bonds are then a sort of compromise; it's a local equilibrium where it would take more energy to smoosh them closer closer together or pull them further apart.

That two electrons can be in the vicinity of positively charged nuclei is not without precedent.
After all, Helium atoms have two electrons orbiting each of them and are stable, even though the electrons repel each other.
 
  • #3
jfizzix said:
Well, to take the simplest example of the bond in a hydrogen molecule, you have two positively charged nuclei, and two electrons. Each electron is attracted to both nuclei, but repelled by the other electron. Chemical bonds are then a sort of compromise; it's a local equilibrium where it would take more energy to smoosh them closer closer together or pull them further apart.

That two electrons can be in the vicinity of positively charged nuclei is not without precedent.
After all, Helium atoms have two electrons orbiting each of them and are stable, even though the electrons repel each other.
But isn't Hydrogen atom electrically neutral? One +p and -e, what is then the attraction between one over the other? Is it not gravity or something?
 
Last edited:
  • #4
bronx said:
But isn't Hydrogen atom electrically neutral? One +p and -e, what is then the attraction between one over the other? Is it not gravity or something?
Forget about gravity. What you have, at long range, is the interaction of the instantaneous dipole. As the two atoms get closer, you will have the electron of one atom having a non-negligible overlap with the nucleus of the other atom.
 
  • Like
Likes bronx
  • #5
DrClaude said:
Forget about gravity. What you have, at long range, is the interaction of the instantaneous dipole. As the two atoms get closer, you will have the electron of one atom having a non-negligible overlap with the nucleus of the other atom.
That's is more real I agree. thanks.
 
  • #6
bronx said:
How is it that in chemical bonding like in covalent bonding electrons form a bond or there is attraction from one unto the other. Isn't that ironic?
There is no attraction between the electrons and mutual repulsion of the electrons is rather an obstacle to bond formation. As others pointed out already, this repulsion is partially made off by the attraction of the nuclei, but this wouldn't explain bonding.
The real reason behind bond formation is a quantum mechanical one: According to Heisenberg's uncertainty relation, the average momentum of an electron will be the lower, the more space it can occupy. Lower momentum also means lower kinetic energy. In a molecule, an electron has the chance to be found on either of two atoms instead of only one before bond formation. Hence it can occupy more space and it's kinetic energy gets lower.
 
  • Like
Likes bronx

FAQ: How Do Electrons Form a Bond in Covalent Bonding Despite Their Mutual Repulsion?

What is electron sharing and bonding?

Electron sharing and bonding is a process in which two or more atoms share electrons in order to achieve a more stable outer electron shell. This results in the formation of chemical bonds between the atoms.

What is the difference between ionic and covalent bonding?

Ionic bonding involves the transfer of electrons from one atom to another, resulting in the formation of ions with opposite charges that are attracted to each other. Covalent bonding, on the other hand, involves the sharing of electrons between atoms, resulting in the formation of molecules.

How does the number of valence electrons affect bonding?

The number of valence electrons an atom has determines its reactivity and ability to form bonds. Atoms with a full outer shell of electrons are stable and do not readily bond with other atoms, while atoms with incomplete outer shells will bond with other atoms in order to achieve a full outer shell.

What is a Lewis dot structure?

A Lewis dot structure is a visual representation of the valence electrons in an atom or molecule. Each dot represents a valence electron, and the structure is used to show the sharing or transfer of electrons between atoms in a bond.

How does electronegativity affect bonding?

Electronegativity is a measure of an atom's ability to attract electrons towards itself in a chemical bond. When two atoms with different electronegativities bond, the more electronegative atom will attract the shared electrons more strongly, resulting in a polar covalent bond.

Similar threads

Replies
16
Views
3K
Replies
8
Views
1K
Replies
11
Views
3K
Replies
6
Views
2K
Replies
5
Views
2K
Replies
7
Views
8K
Replies
8
Views
2K
Back
Top