How Do You Solve the Steady-State Heat Equation for High Activation Energy?

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This is the final solution for the differential equation, as given in the book. The steps taken to arrive at this solution include separation of variables, integration, and rearranging the equation to solve for the exponential term.
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Homework Statement


the math in here is a bit over my head.

the equation is

[tex] \frac {d^2 \theta}{d x'^2 } = -y *exp(\theta) [/tex] eq. 1

first off, this is a steady state model. meaning, we consider the pre-explosion temperature to be small in comparison with the absolute temperature of the walls:[tex] \frac {\Delta T}{T} << 1 [/tex]

2nd, the reaction rate only depends on the deperature in accordance with exp(-E/RT)

3rd we regad the thermal conductivity of the walls as being infinitely large.

x' = x/r is the nondimensionalization of x, r is the half length (i.e radius for cylinder), not the derivative, for -L < x < L we have -1 < x' < 1. x' drops unit (i.e m, cm, ..)

theta is the nondimensionalization of temperature [tex] \theta = \frac {E}{RT^2_a} *(T - T_a) [/tex]

y (although i used a different variable) is known as the frank kamenetskii parameter

[tex] y = \frac {Q}{d}*\frac {E}{R*T^2_a}*r^2*z* exp(\frac {-E}{RT_a}) [/tex]

E: activation energy
T_a: ambient temperature
Q: heat released
z: frequency of particle collision
r: radius or half width (depending on geometry)
R: gas constant
d: thermal conductivity

all uniform except Q, i think..

the book solves the differential equation 1, analytically, for a function [tex] \theta = f(y,x') [/tex] in case of high activation energy E. RT<<E

the book gives the following result.

[tex] exp(\theta) = \frac {a}{cosh^2(b \frac{+}{-} \sqrt \frac{a*y}{2} * x')} [/tex]

im just trying to figure out what steps I need to take in order to arrive at the last solution.seperation of vars?

Homework Equations


The Attempt at a Solution

 
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This equation is a partial differential equation. To solve it, you will need to use the method of separation of variables.The first step is to separate the two variables in the equation. This can be done by writing the equation as:\frac {d^2 \theta}{dx'^2} = -y * exp(\theta)The next step is to integrate both sides of the equation with respect to x'. On the left side, this results in the following equation:\int \frac {d^2 \theta}{dx'^2} dx' = \int -y * exp(\theta) dx'.On the right side, the integral can be solved using the chain rule and the properties of exponentials. This results in the following equation:\frac {d \theta}{dx'} = - \frac{y}{2} exp(\theta) + CAt this point, we can now integrate both sides of the equation with respect to x'. On the left side, this results in the following equation:\int \frac {d \theta}{dx'} dx' = \int - \frac{y}{2} exp(\theta) + C dx'On the right side, the integral can be solved using the chain rule and the properties of exponentials. This results in the following equation:\theta = - \frac{y}{4} exp(\theta)x'^2 + Cx' + DAt this point, we can now rearrange the equation to solve for exp(\theta). This results in the following equation:exp(\theta) = \frac {a}{cosh^2(b \frac{+}{-} \sqrt \frac{a*y}{2} * x')},where a, b, and c are constants.
 

FAQ: How Do You Solve the Steady-State Heat Equation for High Activation Energy?

What is chemical kinetics?

Chemical kinetics is the branch of chemistry that studies the rates of chemical reactions and the factors that influence them.

What is the heat equation?

The heat equation is a mathematical model that describes the distribution of heat in a given system over time. It is commonly used to study the flow of heat and temperature changes in chemical reactions.

How is chemical kinetics related to the heat equation?

Chemical kinetics and the heat equation are closely related because the rate of a chemical reaction is affected by the temperature of the system. The heat equation helps to determine the rate of temperature change in a chemical reaction, which in turn affects the rate of the reaction.

What factors can affect the rate of a chemical reaction?

The rate of a chemical reaction can be affected by factors such as temperature, concentration of reactants, surface area, and the presence of catalysts. These factors influence the frequency of collisions between reactant particles and the energy needed for a successful reaction to occur.

How can chemical kinetics be applied in real life?

Chemical kinetics has many real-life applications, such as in the development of new drugs and medicines, understanding and controlling industrial processes, and studying environmental reactions. It also plays a crucial role in fields such as food science, materials science, and biochemistry.

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