How Does Adding Nitrogen Affect Pressure in a Sealed Vessel?

In summary, the conversation is about calculating the new pressure of a vessel containing nitrogen gas after 0.2 kg is pumped into it. The correct answer is found using the ideal gas law and Dalton's law. The difference in methods used by the student and the instructor does not affect the accuracy of the answer.
  • #1
frozen7
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A vessel of volume 0.2 m^3 contains nitrogen gas at 1.013 bar and 15 celcius. If 0.2 kg of nitrogen is now pumped into the vessel, calculate the new pressure when the vessel has returned to its initial temperature. The molecular weight of nitrogen is 28, and it may be assumed that the gas is a perfect gas. The universal gas constant is 8.314 kNm / kmoleK

I solve it in this way:

PV = nRT
P= nRT / V
= 200/28 x 8.314 x 288 x 1 / 0.2
= 85515 Pa
= 0.855bar

New pressure = 0.855bar + 1.013 bar
= 1.87 bar

The answer I get is same with the given correct answer. However, my lecturer told me that my solution is wrong even I got my final answer correctly. Can anyone explain to me what`s the reason?
Thanks in advance.
 
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  • #2
I can't see anything wrong with your solution. You're simply using Dalton's law here, which should be ok. Did your lecturer comment on where your mistake exactly was?
 
  • #3
Perhaps the instructor is expecting one to calculate the intial number of moles of N2 and then calculate the number of moles added, rather than using partial pressures.
 
  • #4
He told me that because I assume the temperature is constant. The way he solves the problem is by finding the total mass of the nitrogen gas at the final moment and count the pressure by using ideal gas law.
 
  • #5
Anyway, is my way to solve the problem correct?
 
  • #6
Your way is correct. It's actually a bit more to the point. Your instructor did the long way around which is just a different way to do it.

Just because it is not the same method as your instructor's doesn't mean it isn't correct. You didn't get marked down, did you? That wouldn't be right unless it was specified how the problem should be approached.
 

FAQ: How Does Adding Nitrogen Affect Pressure in a Sealed Vessel?

What is a thermodynamics reaction?

A thermodynamics reaction is a chemical reaction that involves the transfer of energy between a system and its surroundings. This energy can take the form of heat, work, or a combination of both. Thermodynamics reactions are governed by the laws of thermodynamics, which describe the relationships between energy, temperature, and entropy.

How do you determine if a thermodynamics reaction is spontaneous?

A thermodynamics reaction is spontaneous if it occurs without the input of external energy. This can be determined by calculating the change in Gibbs free energy (ΔG) for the reaction. A negative ΔG indicates a spontaneous reaction, while a positive ΔG indicates a non-spontaneous reaction.

What is the difference between exothermic and endothermic thermodynamics reactions?

An exothermic thermodynamics reaction releases energy in the form of heat to its surroundings, resulting in a decrease in the system's internal energy. On the other hand, an endothermic thermodynamics reaction absorbs energy from its surroundings, resulting in an increase in the system's internal energy.

How does temperature affect the rate of a thermodynamics reaction?

In general, an increase in temperature will increase the rate of a thermodynamics reaction. This is because an increase in temperature leads to an increase in the kinetic energy of the reactant molecules, causing them to collide more frequently and with greater energy, leading to a faster reaction rate.

What is the role of entropy in thermodynamics reactions?

Entropy is a measure of the disorder or randomness of a system. In thermodynamics reactions, the overall change in entropy (ΔS) is a contributing factor in determining the spontaneity of a reaction. A positive ΔS indicates an increase in disorder, which can drive a reaction towards spontaneity, while a negative ΔS indicates a decrease in disorder, which can hinder spontaneity.

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