How does Le Chatelier's Principle work?

In summary, the principle of Le Chatelier states that if a chemical system at equilibrium experiences a change in concentration, temperature, volume, or partial pressure, the equilibrium will shift to counteract the change. In the conversation, it is suggested that a change in pressure would result in a decrease in the number of molecules, causing a decrease in pressure. However, the kinetic energy of the molecules remains constant, so the pressure should not be affected. It is also noted that not all reactions are equilibrium reactions and the details of the pressure change would determine the outcome.
  • #1
alingy1
325
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It is said that if there is a change in pressure in an equilibrium state, the chemical reactions that diminish the number of molecules will be favorised. Therefore, there will be less molecules, so the pressure will decrease to reach equilibrium again.

However, since the kinetic energy of the molecules doesn't change before and after the reactions, if there are less molecules, those molecules will be slower but heavier. So, according to me, the pressure wouldn't change because the collisions will be less but each collision will apply more force.

What do you think about that?
 
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  • #2
I suspect you have slightly misstated the principle:
If a chemical system at equilibrium experiences a change in concentration, temperature, volume, or partial pressure, then the equilibrium shifts to counteract the imposed change and a new equilibrium is established.
http://en.wikipedia.org/wiki/Le_Chatelier's_principle

... that makes sense since it is an equilibrium reaction that is being considered.
It is possible to have reactions that are not equilibrium reactions.

Per your example - the details depend on how the pressure is changed.
 
  • #3
alingy1 said:
the kinetic energy of the molecules doesn't change before and after the reactions

It doesn't?
 

FAQ: How does Le Chatelier's Principle work?

What is Le Chatelier's Principle?

Le Chatelier's Principle is a principle in chemistry that explains how a system at equilibrium will respond to changes in temperature, pressure, or concentration of reactants or products.

How does Le Chatelier's Principle work?

Le Chatelier's Principle states that when a system at equilibrium is disturbed by a change in temperature, pressure, or concentration, the system will shift in order to counteract the disturbance and re-establish equilibrium.

What factors can cause a system to shift according to Le Chatelier's Principle?

A system can shift due to changes in temperature, pressure, or concentration of reactants or products. These changes can be caused by adding or removing heat, changing the volume or pressure of the system, or adding or removing reactants or products.

How does Le Chatelier's Principle apply to chemical reactions?

Le Chatelier's Principle can be used to predict how a chemical reaction will shift in response to changes in temperature, pressure, or concentration. It can also be used to manipulate the conditions of a reaction in order to increase the yield of desired products.

What is an example of Le Chatelier's Principle in action?

One example of Le Chatelier's Principle is when the concentration of a reactant in a chemical reaction is increased, causing the reaction to shift towards the products in order to balance out the increase in reactants. This results in an increase in the yield of products.

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