How to calculate initial concentration

In summary, a known mass of methylamine, CH3NH2, was dissolved in water at 25 celsius. 50.0 cm^3 of this solution was titrated with 1.00x10^-1 mol dm^-3 hydrochloric acid solution, HCL(aq), and the change in pH as the acid was added is shown in the graph. Using the equations n=m/Mr and n=cv, it can be determined that the initial concentration of CH3NH2 was 0.05 mol dm^-3.
  • #1
D.J Falcon
9
0

Homework Statement


A known mass of methylamine, CH3NH2, was dissolved in water at 25 celsius

50.0 cm^3 of this solution was taken and titrated with 1.00x10^-1 mol dm^-3 hydrochloric acid solution, HCL(aq). The change in pH as an increasing volume of hydrochloric acid was added is shown in the graph below: (Didn't scan the graph)

Homework Equations


These are the equations I think are relevant.
n=m/Mr
n=cv

The Attempt at a Solution


I'm quite lost at what to do from here so help would be appreciated.
 
Last edited:
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  • #2
Is this right? If so, I'm ashamed of meself.

moles HCl=0.1x0.025=0.0025
Initial concentration CH3NH2=0.0025/0.05=0.05
 
  • #3
your working seems correct, given that the endpoint of the titration was at 25 mL added acid. Remember that we do not have access to the unscanned pH curve for the titration.

The other point that I would take issue with is that it would be a good idea to show a few units in your answer, and maybe even in your working.
 

FAQ: How to calculate initial concentration

How do you calculate initial concentration from a given absorbance value?

The initial concentration can be calculated using the Beer-Lambert Law, which states that the concentration of a solution is directly proportional to its absorbance. The formula is C = A/εl, where C is the initial concentration, A is the absorbance, ε is the molar absorptivity, and l is the path length of the cuvette. Simply plug in the values and solve for C.

What is the importance of knowing the initial concentration of a solution?

The initial concentration of a solution is crucial in determining the amount of solute present in a given volume. It is also used to calculate the final concentration after a dilution or reaction has taken place. Additionally, knowing the initial concentration allows for the determination of reaction rates and equilibrium constants.

Can initial concentration be calculated without knowing the absorbance?

No, the initial concentration cannot be calculated without knowing the absorbance. The absorbance is a measure of how much light is absorbed by a solution and is directly proportional to the concentration according to the Beer-Lambert Law.

How do you calculate initial concentration if the solution is not a clear liquid?

If the solution is not a clear liquid, the absorbance can still be measured using a spectrophotometer, which can account for the turbidity or color of the solution. The absorbance value can then be used in the Beer-Lambert Law to calculate the initial concentration.

Can the initial concentration of a solution change over time?

Yes, the initial concentration of a solution can change over time due to factors such as evaporation, chemical reactions, or dilution. It is important to measure the initial concentration at the beginning of an experiment and monitor any changes that may occur.

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