How to normalize Schrodinger equation

In summary, the Schrodinger equation can be normalized by finding a wave function that satisfies the equation and then multiplying it by a normalization constant to ensure that the probability of finding the particle in any location is equal to 1. This process involves solving for the energy levels and wave functions of the system, and then using the normalization condition to determine the appropriate constant. Normalizing the Schrodinger equation allows for the accurate prediction of the behavior of quantum particles and is a fundamental concept in quantum mechanics.
  • #1
warnexus
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Homework Statement



The solution to the Schrodinger equation for a particular potential is psi = 0 for absolute x > a and psi = Asin(pi*x/a) for -a <= x <= a, where A and a are constants. In terms of a, what value of A is required to normalize psi?

Homework Equations



psi = 0 for absolute value of > a
psi = Asin(pi*x/a) for -a<= x <= a

The Attempt at a Solution



The textbook gave the normalization as:

[integral] psi^2 dx = 1. The integral has upper limit positive infinity and lower limit negative infinity.

Can I just start by taking the integral of both sides of psi = Asin(pi*x/a)?

which makes psi = A-cos(pi*x/a) * pi*x^2/(2a)?
 
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  • #2
warnexus said:

Homework Statement



The solution to the Schrodinger equation for a particular potential is psi = 0 for absolute x > a and psi = Asin(pi*x/a) for -a <= x <= a, where A and a are constants. In terms of a, what value of A is required to normalize psi?

Homework Equations



psi = 0 for absolute value of > a
psi = Asin(pi*x/a) for -a<= x <= a

The Attempt at a Solution



The textbook gave the normalization as:

[integral] psi^2 dx = 1. The integral has upper limit positive infinity and lower limit negative infinity.

Can I just start by taking the integral of both sides of psi = Asin(pi*x/a)?

which makes psi = A-cos(pi*x/a) * pi*x^2/(2a)?
No.

The integral of ψ(x) from -∞ to +∞ is zero. After all, ψ(x) is an odd function.

(ψ(x))2 ≥ 0 for all x and it's greater than zero for some values of x, so its integral is definitely positive.
 
  • #3
SammyS said:
No.

The integral of ψ(x) from -∞ to +∞ is zero. After all, ψ(x) is an odd function.

(ψ(x))2 ≥ 0 for all x and it's greater than zero for some values of x, so its integral is definitely positive.

How did you know the integral is zero. Why is psi an odd function?
 
  • #4
warnexus said:
How did you know the integral is zero. Why is psi an odd function?
[itex]\displaystyle \Psi(x)=A\sin\left(\frac{\pi x}{a}\right)[/itex]

Therefore, [itex]\displaystyle \ \Psi(-x)=-\Psi(x)\,,\ [/itex] so [itex]\displaystyle \ \Psi(x)\ [/itex] is odd.

That's pretty much beside the point except that it definitely shows that in general, [itex]\displaystyle \ \int \left(f(x)\right)^2\,dx\ne\left(\,\int f(x)\,dx\right)^2\ .[/itex]

Solving your integral may be made easier by noting that [itex]\displaystyle \ \cos(2\theta)=1-2\sin^2(\theta) \ .\ \ [/itex] And solving for sin2(θ) gives [itex]\displaystyle \ \sin^2(\theta)=\frac{1-\cos(2\theta)}{2} \ . \ [/itex]
 
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  • #5
SammyS said:
[itex]\displaystyle \Psi(x)=A\sin\left(\frac{\pi x}{a}\right)[/itex]

Therefore, [itex]\displaystyle \ \Psi(-x)=-\Psi(x)\,,\ [/itex] so [itex]\displaystyle \ \Psi(x)=\ [/itex] is odd.

That's pretty much beside the point except that it definitely shows that in general, [itex]\displaystyle \ \int \left(f(x)\right)^2\,dx\ne\left(\,\int f(x)\,dx\right)^2\ .[/itex]

Solving your integral may be made easier by noting that [itex]\displaystyle \ \cos(2\theta)=1-2\sin^2(\theta) \ .\ \ [/itex] And solving for sin2(θ) gives [itex]\displaystyle \ \sin^2(\theta)=\frac{1-\cos(2\theta)}{2} \ . \ [/itex]

I know I stated -a<= x <= a. But x can be positive or negative. How did you know to choose x to be negative?

How is cos(2θ)=1−2sin2(θ)? I don't remember this being a trig identity. I am weak in math.
 
  • #6

FAQ: How to normalize Schrodinger equation

1. What is the Schrodinger equation?

The Schrodinger equation is a fundamental equation in quantum mechanics that describes the time evolution of a quantum system. It is used to calculate the probability distribution of a particle's position and momentum over time.

2. Why is it important to normalize the Schrodinger equation?

Normalizing the Schrodinger equation ensures that the probability of finding a particle in any location is equal to 1. This is necessary for the equation to accurately describe the behavior of quantum systems.

3. How do you normalize the Schrodinger equation?

To normalize the Schrodinger equation, you must ensure that the wave function, which is a key component of the equation, is a square-integrable function. This means that the integral of the wave function squared over all space must equal 1.

4. What are the consequences of not normalizing the Schrodinger equation?

If the Schrodinger equation is not normalized, it can lead to incorrect predictions about the behavior of quantum systems. For example, it could incorrectly predict a probability greater than 1 for a particle to be found in a certain location.

5. Is there more than one way to normalize the Schrodinger equation?

Yes, there are multiple ways to normalize the Schrodinger equation depending on the specific system being studied. However, all methods involve ensuring that the wave function is a square-integrable function and that the integral of the wave function squared over all space equals 1.

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