How to prove that the L and S (of the total angular momentum commute?

In summary, to prove that the total orbital angular momentum \( L \) and total spin angular momentum \( S \) commute, one can demonstrate that their commutation relation \([L, S] = 0\). This involves showing that the components of \( L \) (which are functions of position and momentum) and \( S \) (which are intrinsic properties of particles) act independently on the quantum state vectors. Since they pertain to different degrees of freedom, their operators do not interfere with each other, leading to the conclusion that they commute, which is essential for analyzing systems with both orbital and spin angular momentum in quantum mechanics.
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  • #2
In non-relativstic theory all three spin-component operators commute with ##\hat{\vec{x}}## and ##\hat{\vec{p}}## and thus ##\hat{\vec{S}}^2## and ##\hat{S}_3## can be used as two additional compatible observables in addition to ##\hat{H}##, ##\hat{\vec{L}}^2##, and ##\hat{L}_3##. By the usual construction these common eigenvectors ##|E,L,m,s,\sigma \rangle## span the quantum-mechanical Hilbert space of a particle with spin.

The relativistic case is much more involved. Spin and orbital angular momentum cannot be distinguished. The observables are rather total angular momentum and "polarization states" (Pauli-Lubanski vector).
 
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  • #3
If L and S commute one can find a commun basis in which they would be diagonal
Son on this diagonal we would find 2 discrete values of S and the eigenvalues of L.
What is the mistake?
 
  • #4
Heidi said:
If L and S commute one can find a commun basis in which they would be diagonal
Son on this diagonal we would find 2 discrete values of S and the eigenvalues of L.
What is the mistake?
L and S act on different Hilbert spaces. If you want to study them combined, then you need to use the tensor product of those Hilbert spaces, as your new Hilbert space on which those operators are appropriately defined.
 
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  • #5
As I said, a complete basis, spanning the Hilbert space of a single particle with spin ##s## is given by, e.g.,
$$| |\vec{p}|,\ell,m,s,\sigma \rangle$$
with ##|\vec{p}| \in \mathbb{R}_{\geq 0}##, ##\ell \in \mathbb{N}_0##, ##m \in \{-\ell,-\ell+1,\ldots,\ell-1,\ell \}##, ##s \in \mathbb{N}_0/2##, ##\sigma \in \{-s,-s+1,\ldots,s-1,s \}##.

A "wave function" can then be represented wrt. this basis,
$$\psi_\sigma(|\vec{p}|,\ell,m,s)=\langle |\vec{p}|,\ell,m,s,\sigma|\psi \rangle.$$
 
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  • #6
  • #7
I don't see the statement there, although my French is very limited. Of course, you can as well have another complete set, i.e., with ##\vec{J}=\vec{L}+\vec{S}##, you can use ##\hat{\vec{J}}^2##, ##\hat{\vec{L}}^2##, ##\hat{\vec{S}}^2##, and ##\hat{J}_3## as a complete set of angular-momentum observables. It's just a basis transformation from the complete orthonormal set to this other one, introducing the corresponding Clebsch-Gordon coefficients dealing with the addition of two independent angular momenta (as here orbital and spin angular momentum of a non-relativistic particle).
 
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  • #8
the french sentence is:
il convient de remarquer que le terme
{\displaystyle {\vec {L}}\cdot {\vec {S}}}
ne commute pas avec
{\vec  {L}}
et
{\vec  {S}}

google translate gives:
it should be noted that the term L.S does not commute with L and S (with arrows)
i agree that we can take the tensor product of the two Hilbert spaces (on which they act separately) to get one Hilbert space on which L ans S act. But how do you compure [L,S] to see if they commute?
 
  • #9
Heidi said:
the french sentence is:
il convient de remarquer que le terme
{\displaystyle {\vec {L}}\cdot {\vec {S}}}
ne commute pas avec
{\vec  {L}}
et
{\vec  {S}}

google translate gives:
it should be noted that the term L.S does not commute with L and S (with arrows)
i agree that we can take the tensor product of the two Hilbert spaces (on which they act separately) to get one Hilbert space on which L ans S act. But how do you compure [L,S] to see if they commute?
Denote the space on which L acts as ##\Lambda## and the space S acts on as ##\Sigma##, with the usual eigen-relations.

Then we can act L and S on the tensor product space ##\Lambda \bigotimes \Sigma##. If I have my notation right:

##[L, S] ( \lambda \otimes \sigma ) \equiv ( L \bigotimes S ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle - ( S \bigotimes L ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle##

##= \lambda \sigma ( L \bigotimes S ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle - \sigma \lambda ( S \bigotimes L ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle##

##= ( \lambda \sigma - \sigma \lambda ) ( L \bigotimes S ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle##

##= 0##

Because the two spaces are independent, the eigenvalue relations will only act on those individual spaces, so commutativity is almost trivial.

-Dan
 
  • #10
I leave out the hats. All angular-momentum components are operators in this posting.

We have
$$[L_j,L_k]=\mathrm{i} \epsilon_{jkl} L_l, \quad [S_j,S_k]=\mathrm{i} \epsilon_{jkl} S_l, \quad [L_j,S_k]=0.$$

Of course from this it follows that the ##\vec{L} \cdot \vec{S}## doesn't commute with ##\vec{L}## and also not with the ##\vec{S}## but with the ##\vec{J}##:
$$[L_j,L_k S_k]=[L_j,L_k]S_k+L_k [L_j,S_k]=\mathrm{i} \epsilon_{jkl} L_l S_k=\mathrm{i} (\vec{S} \times \vec{L})_j,$$
$$[S_j,L_k S_k]=[S_j,L_k]S_k + L_k [S_j,S_k] = L_k \mathrm{i} \epsilon_{jkl} S_l = \mathrm{i} (\vec{L} \times \vec{S})_j$$
and from that
$$[S_j,L_k S_k]=0.$$
So you can have the above mentioned new cons of common eigenvectors for ##\vec{J}^2##, ##\vec{L}^2##, ##\vec{S}^2##, and ##J_z##.
 
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  • #11
topsquark said:
Denote the space on which L acts as ##\Lambda## and the space S acts on as ##\Sigma##, with the usual eigen-relations.

Then we can act L and S on the tensor product space ##\Lambda \bigotimes \Sigma##. If I have my notation right:

##[L, S] ( \lambda \otimes \sigma ) \equiv ( L \bigotimes S ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle - ( S \bigotimes L ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle##

##= \lambda \sigma ( L \bigotimes S ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle - \sigma \lambda ( S \bigotimes L ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle##

##= ( \lambda \sigma - \sigma \lambda ) ( L \bigotimes S ) \mid \lambda \rangle \, \otimes \mid \sigma \rangle##

##= 0##

Because the two spaces are independent, the eigenvalue relations will only act on those individual spaces, so commutativity is almost trivial.

-Dan
The point is that ##\vec{L} \cdot \vec{S}## acts on both products of the tensor product. There's no contradiction that neither ##\vec{L}## nor ##\vec{S}## commute with this spin-orbit term, but on the other hand it's a scalar quantity, and thus it must commute under rotations, and rotations are generated by the total angular momentum operators, i.e., ##\vec{J}=\vec{L}+\vec{S}##.
 
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  • #12
Is the french wiki's sentence false?
 
  • #13
No, why? It states what I've proved in #10. How do you come to the conclusion that ##\vec{L} \cdot \vec{S}## should commute with the ##\vec{L}## and/or the ##\vec{S}## components? It's a scalar under rotations, and rotations are represented by ##\vec{J}=\vec{L}+\vec{S}##, and indeed it commutes with ##\vec{J}## as it should be for a scalar.
 
  • #14
I would like to be able to manipulate the algebra of opérators and the Hilbert space machinary With just the separable l2 global Hilbert space.
there is an hilbertian basis. an inner scalar product ans so on
How do you define L.S operator? What is this dot berween operators? of course it is not the scalar product between vectors. Is it a scalar product in the C* algebra?
And how to calculate [L, L.S] and give its non null value?
 
  • #15
Heidi said:
I would like to be able to manipulate the algebra of opérators and the Hilbert space machinary With just the separable l2 global Hilbert space.
Only ##L## is an operator in this space; ##S## is not. So you can't even frame any questions about ##S##, or any expression involving ##S##, if you restrict yourself to this Hilbert space.
 
  • #16
Heidi said:
What is this dot berween operators? of course it is not the scalar product between vectors
Yes, it is the scalar product between vectors--vectors of operators. The vector ##L## has components ##L_x##, ##L_y##, and ##L_z##, and the vector ##S## has components ##S_x##, ##S_y##, and ##S_z##. The dot product then works just like you would expect.
 
  • #17
Heidi said:
And how to calculate [L, L.S] and give its non null value?
@vanhees71 already showed you how to do that in post #10.
 
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  • #18
thank you for the answers. I understant now.
 

FAQ: How to prove that the L and S (of the total angular momentum commute?

What is the significance of proving that L and S commute?

Proving that the orbital angular momentum (L) and the spin angular momentum (S) commute is crucial because it implies that these two quantities can be measured simultaneously with definite values. This is important in quantum mechanics as it allows for the construction of a complete set of commuting observables, which in turn helps in solving the Schrödinger equation for systems like electrons in atoms.

What is the mathematical definition of commutation in this context?

In quantum mechanics, two operators A and B are said to commute if their commutator [A, B] = AB - BA equals zero. For the total angular momentum, we need to show that [L, S] = 0, meaning the orbital angular momentum operator L and the spin angular momentum operator S can be applied in any order without affecting the outcome.

How do you prove that the components of L and S commute?

The proof involves showing that each component of the orbital angular momentum (Lx, Ly, Lz) commutes with each component of the spin angular momentum (Sx, Sy, Sz). This is typically done by using the commutation relations for angular momentum operators and the fact that L acts on spatial coordinates while S acts on internal spin coordinates. Since these sets of coordinates are independent, their operators commute.

What are the commutation relations for the components of L and S?

The commutation relations for the components of the orbital angular momentum L are [Lx, Ly] = iħLz, [Ly, Lz] = iħLx, and [Lz, Lx] = iħLy. Similarly, for the spin angular momentum S, the commutation relations are [Sx, Sy] = iħSz, [Sy, Sz] = iħSx, and [Sz, Sx] = iħSy. To prove that L and S commute, we need to show that [Li, Sj] = 0 for all i and j.

Can you provide an example of the commutation proof for specific components?

Consider the commutation of Lz and Sx. Using the definitions and commutation relations:[Lz, Sx] = LzSx - SxLz.Since Lz acts only on spatial coordinates and Sx acts only on spin coordinates, they operate in different Hilbert spaces. Therefore, LzSx = SxLz, implying that [Lz, Sx] = 0. Similar calculations can be performed for other components to show that [Li, Sj] = 0 for all i and j.

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