How to turn partition sum into an integral?

In summary, turning a partition sum into an integral involves taking the limit of a Riemann sum as the number of partitions approaches infinity. This process typically includes defining a function that represents the sum over a partition of an interval, then expressing the sum in terms of the function values at specific points multiplied by the width of the partitions. As the partition width narrows, the sum converges to the integral of the function over the specified interval, effectively translating the discrete summation into a continuous integral representation.
  • #1
LightPhoton
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Homework Statement
How to evaluate partition sum in the limit where $$kT\gg\epsilon$$
Relevant Equations
$$Z_{tot}=\sum_0^\infty (2j+1)e^{-j(j+1)\epsilon/kT}$$
In, *An Introduction to Thermal Physics, page 235*, Schroder wants to evaluate the partition function

$$Z_{tot}=\sum_0^\infty (2j+1)e^{-j(j+1)\epsilon/kT}$$

in the limit that $kT\gg\epsilon$, thus he writes

$$Z_{tot}\approx\int_0^\infty (2j+1)e^{-j(j+1)\epsilon/kT}\,dj$$

But how is this correct? There was no factor of $j$ in the sum that could be replaced with $dj$. Also, it is good that $j$ is just a number, otherwise even the dimensions of $Z_{tot}$ would be wrong.
 
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  • #2
LightPhoton said:
There was no factor of ##j## in the sum that could be replaced with ##dj##.
Yes, there is such a factor if you express "##1##" in terms of the summation index "##j##":$$Z_{tot}=\sum_{0}^{\infty}(2j+1)e^{-j(j+1)\epsilon/kT}\times1=\sum_{0}^{\infty}(2j+1)e^{-j(j+1)\epsilon/kT}\left((j+1)-j\right)\equiv\sum_{0}^{\infty}(2j+1)e^{-j(j+1)\epsilon/kT}\triangle j$$Now can you see how the integral approximates the sum?
 
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FAQ: How to turn partition sum into an integral?

What is a partition sum?

A partition sum is a mathematical expression that represents the sum of all possible configurations or states of a system, often used in statistical mechanics and quantum field theory. It accounts for the contributions of all microstates to the macroscopic properties of a system.

How does one relate a partition sum to an integral?

To relate a partition sum to an integral, one typically uses the principle of the continuum limit. As the number of states increases and the spacing between them becomes infinitesimally small, the sum can be approximated by an integral. This is often done by replacing the discrete state variables with continuous variables and using techniques such as the Riemann sum approach.

What are the conditions for turning a partition sum into an integral?

The primary conditions for turning a partition sum into an integral include having a large number of states, the states being densely packed, and the function being smooth enough over the region of interest. Additionally, the temperature and other parameters should be such that the system can be effectively described by thermodynamic principles.

Can you give an example of turning a partition sum into an integral?

An example is the canonical partition function in statistical mechanics, given by the sum over all energy states: Z = Σ e^(-βE_i). In the limit of a large number of states, this sum can be approximated by an integral: Z ≈ ∫ e^(-βE(x)) dx, where E(x) represents the energy as a continuous variable and β is the inverse temperature.

What is the significance of this transformation in physics?

The transformation from a partition sum to an integral is significant because it allows physicists to apply calculus and analytical techniques to derive macroscopic properties from microscopic behavior. This approach facilitates the calculation of thermodynamic quantities such as free energy, entropy, and specific heat in a more tractable manner.

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