- #1
LightPhoton
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- Homework Statement
- How to evaluate partition sum in the limit where $$kT\gg\epsilon$$
- Relevant Equations
- $$Z_{tot}=\sum_0^\infty (2j+1)e^{-j(j+1)\epsilon/kT}$$
In, *An Introduction to Thermal Physics, page 235*, Schroder wants to evaluate the partition function
$$Z_{tot}=\sum_0^\infty (2j+1)e^{-j(j+1)\epsilon/kT}$$
in the limit that $kT\gg\epsilon$, thus he writes
$$Z_{tot}\approx\int_0^\infty (2j+1)e^{-j(j+1)\epsilon/kT}\,dj$$
But how is this correct? There was no factor of $j$ in the sum that could be replaced with $dj$. Also, it is good that $j$ is just a number, otherwise even the dimensions of $Z_{tot}$ would be wrong.
$$Z_{tot}=\sum_0^\infty (2j+1)e^{-j(j+1)\epsilon/kT}$$
in the limit that $kT\gg\epsilon$, thus he writes
$$Z_{tot}\approx\int_0^\infty (2j+1)e^{-j(j+1)\epsilon/kT}\,dj$$
But how is this correct? There was no factor of $j$ in the sum that could be replaced with $dj$. Also, it is good that $j$ is just a number, otherwise even the dimensions of $Z_{tot}$ would be wrong.