Ideal gas and dimensionless entropy.

In summary, the person is trying to solve an exercise, but is not sure how to proceed. They have found their way using the relations provided, but are not sure how to use the entropy. They are very close to solving the problem.
  • #1
ted1986
22
0
Hi,

I'm trying to solve the attached exercise, but I'm not sure I'm in the right direction.
What I've been trying to do is using the relation:
dU=TdS-pdV
Dividing it by T and adding dT so the relation will be
(dU/T)dT=(ds/dT)-pT(dVdT), but I don’t think it’s the right way to solve it.

Can someone help me?

thnks.
 

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  • #2
Start with your expression for dU, and solve it for dS. Then figure out how changes in rho, called d rho, depend on changes in V, called dV. Now figure out how U, the energy, depends on T, V, and rho, which requires you to look up formulas for how both gas and radiation energy depend on these quantities. Once you have that, add the two U contributions together, factor out the gas contribution (that's where you will get the sigma coming in), and find dU.
 
  • #3
By the way, it will help you quite a bit to know that:
U = (3 Pr + 3/2 Pg) V
so
dU = (3 dPr + 3/2 dPg) V + (3 Pr + 3/2 Pg) dV
and then you will also need the ideal gas law for Pg and the fact that
dPr/Pr = 4 dT / T.
Do you know things like:
drho / rho = - dV / V ? That's the kind of expression you'll need to understand well.
You have yourself a challenging problem, try to find expressions like dT/T and drho/rho, and factor out a Pg when you get to the end, that's where sigma comes in. I think you will find this exercise pretty challenging, but it contains a lot of the skills you need now.
 
  • #4
Ken G said:
By the way, it will help you quite a bit to know that:
U = (3 Pr + 3/2 Pg) V
so
dU = (3 dPr + 3/2 dPg) V + (3 Pr + 3/2 Pg) dV
and then you will also need the ideal gas law for Pg and the fact that
dPr/Pr = 4 dT / T.
Do you know things like:
drho / rho = - dV / V ? That's the kind of expression you'll need to understand well.
You have yourself a challenging problem, try to find expressions like dT/T and drho/rho, and factor out a Pg when you get to the end, that's where sigma comes in. I think you will find this exercise pretty challenging, but it contains a lot of the skills you need now.


Thank you for your answer.
I used the relations you wrote, and it looks like I'm in the right direction, but as you can see in the attached file – I don’t know how to use the entropy dS instead of dU.

B.T.W - Where can I find explanations about the relations you wrote?
Thank you.
 

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  • #5
Yes, that's looking pretty good-- now solve your final expression for dS and look for a way to replace some stuff with the Boltzmann k (which you then absorb into dS because they are using the dimensionless entropy and we are not). The place to look for these kinds of relations is in regular gas dynamics textbooks, it is what underlies the ideal gas laws.
 
  • #6
Ken G said:
Yes, that's looking pretty good-- now solve your final expression for dS and look for a way to replace some stuff with the Boltzmann k (which you then absorb into dS because they are using the dimensionless entropy and we are not). The place to look for these kinds of relations is in regular gas dynamics textbooks, it is what underlies the ideal gas laws.


OK, I expressed dS, but it looks different from the final term (File is attached).
Another question - the p (from the relation TdS-pdV=dU) - is it the total pressure? and if it is, how is it expressed?
 

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  • #7
You're very close. Note that dividing through by nR (or Nk, which is the same thing) is what turns the total dS into a dimensionless dS per particle (which is what they mean by dS). In P dV, the P is the total pressure, so Pg + Pr. That should make sense to you-- the work done doesn't care what flavor of pressure is doing it, and the thermodynamic equilibrium insures that radiation and gas will share the energy to be at the same T.
 
  • #8
Solved!

Thank you so much!
 

FAQ: Ideal gas and dimensionless entropy.

What is an ideal gas?

An ideal gas is a theoretical gas that follows the gas laws perfectly. It is made up of particles that have no volume and do not interact with each other. This means that an ideal gas has a constant temperature, pressure, and volume relationship, and its behavior can be accurately described by the ideal gas law.

What is dimensionless entropy?

Dimensionless entropy is a measure of the randomness or disorder of a system. It is a ratio of the system's entropy to its absolute temperature, and it has no units. This allows for easier comparison of entropy values between different systems.

How is ideal gas behavior related to dimensionless entropy?

Ideal gas behavior is closely related to dimensionless entropy. As an ideal gas expands, its particles become more disordered, which increases the dimensionless entropy. This is because the particles are spreading out and their positions become less predictable.

Can dimensionless entropy be negative?

No, dimensionless entropy cannot be negative. It is a measure of disorder, and a negative value would imply a negative level of disorder, which is not possible. Entropy can only increase or remain constant, it cannot decrease.

How is dimensionless entropy used in thermodynamics?

Dimensionless entropy is used in thermodynamics to determine the direction of spontaneous processes. A system will tend towards a state of maximum entropy, meaning that the dimensionless entropy will increase. This helps to predict the direction of energy flow and the behavior of systems in different conditions.

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