Internal energy of any ideal gas

In summary, the internal energy of a monoatomic ideal gas is solely determined by the temperature, as calculated using the Boltzmann Maxwell distribution. This is due to the fact that monoatomic gases only have translational motion, meaning there are no rotational or vibrational energies present. However, this is only an approximation as multiatomic gases do have additional degrees of freedom and therefore their internal energy also depends on temperature, but with a different constant. This can be expressed through the equation U=nC_{V,m}T, where n is the number of moles, C_{V,m}=\frac f2 R is the molar heat capacity, and f is the number of degrees of freedom. For real gases, the relationship between internal
  • #1
Pushoam
962
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The internal energy of monoatomic ideal gas is due to the kinetic energy of the molecules.
Using Boltzmann Maxwell distribution, it is calculated that the kinetic energy due to translational motion of gas molecules of an ideal gas depends only on the temperature.
In case of monoatomic gas, since the molecules can have only transational motion, the internal energy depends only on the temperature.

But, it is said that the internal energy of any ideal gas depends upon only on the temperature. Is it an approximation?
 
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  • #2
Multiatomic gasses also have rotational kinetic energy and vibrational energy.
That is, they have more degrees of freedom.
Otherwise the same things apply.
It means that the internal energy indeed depends only on temperature - just with a different constant.
$$U=n C_{V,m}T$$
where ##n## is the number of moles, ##C_{V,m}=\frac f2 R## is the molar heat capacity, and ##f## is the number of degrees of freedom (f=3 for monatomic ideal gasses, f=5 for diatomic ideal gasses).
For real gasses it's of course a little more complicated.
See for instance Heat Capacity on wiki.
 
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  • #3
Thank you.
 

Related to Internal energy of any ideal gas

What is internal energy?

The internal energy of any ideal gas refers to the total energy contained within the gas due to the motion and interactions of its molecules. It includes the kinetic energy of the molecules as well as the potential energy due to their interactions.

How is internal energy related to temperature?

According to the ideal gas law, temperature is directly proportional to the average kinetic energy of the gas molecules. Therefore, as temperature increases, the internal energy of the gas also increases.

What factors affect the internal energy of an ideal gas?

The internal energy of an ideal gas is affected by its temperature, pressure, and volume. Additionally, the number of molecules in the gas and the type of gas also play a role in determining its internal energy.

Can internal energy be changed by adding or removing heat?

Yes, the internal energy of an ideal gas can be changed by adding or removing heat. When heat is added, the molecules in the gas gain kinetic energy, increasing the internal energy. Conversely, removing heat decreases the internal energy of the gas.

How is the internal energy of an ideal gas calculated?

The internal energy of an ideal gas can be calculated using the equation U = (3/2) nRT, where U is the internal energy, n is the number of moles of gas, R is the gas constant, and T is the temperature in Kelvin. This equation assumes that the gas is in a constant pressure and volume system.

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