Interpreting enthelpy on a ph diagram

In summary, the conversation is about analyzing a vapor compression refrigeration cycle and the confusion surrounding the use of positive and negative values in the equations. There is also a discussion about the use of arrows on the equations and the convention used for labeling the levels in the cycle.
  • #1
influx
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2

Homework Statement


8e02c9.png

2. Homework Equations

q = w+Δh

The Attempt at a Solution



I fail to understand how they obtained the 3 equations at the bottom. For the first one I understand that q = Δh since w = 0 but why is it h1-h4 rather than the other way around? Also, why does this h1-h4 equal h14 rather than h41? Is there some sort of convention? If yes, why isn't it followed with the next line which is h3-h2 = -h23 ? Similarly, why is Win = h1-h2 rather than the opposite way and why does this equal -h12?

Later on in the lecture it says:

2eecde.png


so now qh = h2-h3 ? So is it h3-h2 or the other way round?
 
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  • #2
Hello,

This looks like an analysis of a vapour compression refrigeration cycle.
If there is no explanatory context, then that's didactically not very good. Good books tend to clearly define what's positive and what's negative, but here it has to be picked up from the context. And the double arrows on the red lines with e.g. h23 are very unhelpful ! They should have used arrows on the right hand side only.

As a physicist I am used to read from left to right so ##\tau_{21}## is the lifetime of level 2 for transition to level 1.

And here it looks like use the same convention: h41 = h4 - h1 = - h14

At least they do it consistently, e.g. : h4 = h1 + h14 and h2 = h1 + h12
 
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FAQ: Interpreting enthelpy on a ph diagram

What is entropy on a ph diagram?

Entropy is a measure of the disorder or randomness in a system. In the context of a pH diagram, it represents the degree of randomness in the distribution of hydrogen ions (H+) and hydroxide ions (OH-) in a solution.

How is entropy related to pH?

Entropy and pH are inversely related. As pH increases, the concentration of H+ ions decreases, causing a decrease in entropy. Conversely, as pH decreases, the concentration of H+ ions increases, resulting in an increase in entropy.

What information can be gained from interpreting entropy on a pH diagram?

Interpreting entropy on a pH diagram can provide information about the stability and behavior of a solution. It can also reveal the dominant chemical species present and the potential for reactions to occur.

How is enthalpy related to entropy on a pH diagram?

Enthalpy and entropy are both thermodynamic properties that describe the state of a system. On a pH diagram, enthalpy represents the heat energy released or absorbed during a chemical reaction, while entropy represents the randomness of the system.

How can understanding entropy on a pH diagram be useful in practical applications?

Interpreting entropy on a pH diagram is useful in many practical applications, such as understanding the stability of solutions, predicting the direction of reactions, and designing chemical processes. It can also aid in the identification of suitable conditions for reactions and the optimization of chemical processes.

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