Is bronze tarnish electrochemical corrosion or chemical corrosion?

In summary, the conversation discusses the definitions of chemical and electrochemical corrosion and how they can be applied to the reaction between bronze and air. It is explained that the classification of a reaction as chemical or electrochemical depends on the physical location of the atoms involved and the movement of charges. It is concluded that the reaction between bronze and air would be classified as a chemical reaction due to the physical contact between the atoms. However, the process of metal corrosion can also involve both chemical and electrochemical reactions, making it difficult to classify definitively.
  • #1
Yeahaight
10
0
Homework Statement
Is bronze tarnish electrochemical corrosion or chemical corrosion?
Bronze is outside, reacting with air.
Relevant Equations
no
I can't figure it out.
 
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  • #2
What definitions of chemical and electrochemical corrosion are you expected to use?

My bet is that it is one of these cases where an attempt at classification is futile and a waste of time.
 
  • #3
Yeahaight said:
Homework Statement:: Is bronze tarnish electrochemical corrosion or chemical corrosion?
Bronze is outside, reacting with air.
Relevant Equations:: no

I can't figure it out.
Since all chemical reactions are rearrangements of atoms due to electric forces, whether a reaction is considered chemical or electrochemical depends on how it occurs, not what it results in.

My understanding is that if the reaction occurs with the atoms of both elements physically together at the same location then it would be classified as a chemical reaction. If there is a distance between the atoms of both elements so that the electronic reconfiguration occurs at a physically separate distances with the bonds between the two atoms resulting from the movement of ions and electrons from physically separate locations, then it is classified as electrochemical (since movement of charges - ions and electrons - constitutes an electric current).

Since tarnish occurs because the oxygen atoms in the air come into contact with the copper atoms in the bronze surface, it would be classified as a chemical reaction.

AM
 
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  • #4
Trick is, metal corrosion often happens with red and ox counterparts being separated and charge being transferred between them through metal and electrolytes - that why salty water speeds up this type of corrosion (by making it easier to transfer the charge). Then, despite everything being in place, the process is definitely electrochemical. As there can be any combination of reactions, classifying arbitrarily "this is chemical" or "this is electrochemical" is in some cases either difficult, or futile.
 

FAQ: Is bronze tarnish electrochemical corrosion or chemical corrosion?

What is the difference between electrochemical corrosion and chemical corrosion?

Electrochemical corrosion is a process where metals are corroded through a chemical reaction with their environment, typically involving the presence of water and oxygen. Chemical corrosion, on the other hand, is a process where metals are corroded through direct contact with a corrosive substance, such as acids or salts.

Is bronze tarnish considered electrochemical corrosion or chemical corrosion?

Bronze tarnish is typically considered to be a form of electrochemical corrosion. This is because it is caused by a reaction between the metal and its environment, specifically oxygen and moisture. However, it can also be influenced by chemical factors, such as the presence of sulfur compounds.

What factors contribute to the corrosion of bronze?

The corrosion of bronze can be influenced by a variety of factors, including the presence of oxygen and moisture, exposure to certain chemicals, and the composition of the bronze alloy. The rate of corrosion can also be affected by temperature, pH levels, and the presence of other metals in the environment.

What are some common methods for preventing bronze corrosion?

Some common methods for preventing bronze corrosion include using protective coatings, such as paint or lacquer, to create a barrier between the metal and its environment. Other methods include using corrosion-resistant alloys, controlling the temperature and humidity of the environment, and regularly cleaning and maintaining the bronze surface.

Can bronze corrosion be reversed?

In some cases, bronze corrosion can be reversed through various methods, such as mechanical cleaning, chemical treatment, or electrochemical techniques. However, the effectiveness of these methods may depend on the severity and type of corrosion, as well as the condition of the bronze surface.

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