- #1
Whakataku
- 12
- 0
So I came across a cool toxin, and saw that people have not assigned an IUPAC name to it, so I took on the challenge.
The compound of interest is Batrachotoxinin A
unc.
edu/depts/mtcgroup/litmeetings/batrachotoxinin.pdf
In the second slide Batrachotoxinin A has an R which is an H instead of a pyrolle moiety.
Now Batrachotoxinin A's relative Batrachotoxin (the one with the pyrolle moiety) has the following IUPAC name
1H-Pyrrole-3-carboxylic acid, 2,4-dimethyl-, (1S)-1-[(5aR, 7aR, 9R, 11aS, 11bS, 12R, 13aR)-1,2,3,4,7a,8,9,10,11,11a , 12,13- dodecahydro-9,12-dihydroxy-2, 11a-dimethyl- 7H-9,11b-epoxy-13a, 5a-propenophenanthro[2,1-f] [1,4] oxazepin-14-yl] ethyl ester
So is the Batrachotoxinin A's IUPAC
(1S)-1-[(5aR, 7aR, 9R, 11aS, 11bS, 12R, 13aR)-1,2,3,4,7a,8,9,10,11,11a , 12,13- dodecahydro-9,12-dihydroxy-2, 11a-dimethyl- 7H-9,11b-epoxy-13a, 5a-propenophenanthro[2,1-f] [1,4] oxazepin-14-yl] ethyl ester
(As you can see I just deleted 1H-Pyrrole-3-carboxylic acid, 2,4-dimethyl-,)
is that ok?
The compound of interest is Batrachotoxinin A
unc.
edu/depts/mtcgroup/litmeetings/batrachotoxinin.pdf
In the second slide Batrachotoxinin A has an R which is an H instead of a pyrolle moiety.
Now Batrachotoxinin A's relative Batrachotoxin (the one with the pyrolle moiety) has the following IUPAC name
1H-Pyrrole-3-carboxylic acid, 2,4-dimethyl-, (1S)-1-[(5aR, 7aR, 9R, 11aS, 11bS, 12R, 13aR)-1,2,3,4,7a,8,9,10,11,11a , 12,13- dodecahydro-9,12-dihydroxy-2, 11a-dimethyl- 7H-9,11b-epoxy-13a, 5a-propenophenanthro[2,1-f] [1,4] oxazepin-14-yl] ethyl ester
So is the Batrachotoxinin A's IUPAC
(1S)-1-[(5aR, 7aR, 9R, 11aS, 11bS, 12R, 13aR)-1,2,3,4,7a,8,9,10,11,11a , 12,13- dodecahydro-9,12-dihydroxy-2, 11a-dimethyl- 7H-9,11b-epoxy-13a, 5a-propenophenanthro[2,1-f] [1,4] oxazepin-14-yl] ethyl ester
(As you can see I just deleted 1H-Pyrrole-3-carboxylic acid, 2,4-dimethyl-,)
is that ok?