IUPAC Naming of Organic Compounds: Cis and Trans Isomers with Substituent Groups

In summary, the conversation was discussing the IUPAC names for two different compounds, specifically the difference between Cis-3-secbutyl,1-methylcyclopentane and Cis-1-methyl-3-(1-methyl)propylcyclopentane. While the first compound may seem more clear in its naming, IUPAC naming can be unconventional and the two names are actually referring to the same compound.
  • #1
dolpho
66
0

Homework Statement



Give an acceptable IUPAC name for these compounds.

http://i.imgur.com/tHUpwYK.png

The Attempt at a Solution



So the question is really on the 2nd problem in the picture but I need to reference the first one for my question.

So my original guess on the 2nd problem was. Cis-3-secbutyl, 1-methylcyclopentane

I looked up the answer and it was... Cis-1-methyl-3-(1-methyl)propylcyclopentane

So I sort of understand how naming complex substituent groups work so I applied it to the first question and got... trans 1-(1-methyl)ethyl, 3-methylcyclohexane. The answer to that was trans-1-isopropyl-3-methylcyclohexane.

So just to reiterate my question, is Cis-3-secbutyl,1-methylcyclopentane the same as Cis-1-methyl-3-(1-methyl)propylcyclopentane?

If it's not I'd appreciate any help :D
 
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  • #2
dolpho said:
is Cis-3-secbutyl,1-methylcyclopentane the same as Cis-1-methyl-3-(1-methyl)propylcyclopentane?
Yes. My gut says that "sec butyl" is more informative than 1-methylpropyl (since this is just a butyl chain), but IUPAC is wacky like that.
 

FAQ: IUPAC Naming of Organic Compounds: Cis and Trans Isomers with Substituent Groups

1. What is the purpose of naming organic compounds?

The purpose of naming organic compounds is to provide a systematic and standardized way to identify and communicate the structure and composition of different molecules. This allows scientists to easily understand and compare different compounds, as well as make predictions about their properties and reactions.

2. How are organic compounds named?

Organic compounds are named using a set of rules and guidelines established by the International Union of Pure and Applied Chemistry (IUPAC). These rules take into account the number and arrangement of atoms, functional groups, and other structural features of the molecule.

3. What is the significance of functional groups in naming organic compounds?

Functional groups are specific groups of atoms that determine the chemical and physical properties of a molecule. They are important in naming organic compounds because they provide information about the reactivity and behavior of the molecule, and can help to predict its properties and reactions.

4. What abbreviations are used in naming organic compounds?

There are several common abbreviations used in naming organic compounds, such as "R" for an alkyl group, "X" for a halogen atom, and "Me" for a methyl group. These abbreviations are used to simplify and shorten the names of complex molecules.

5. How do you name organic compounds with multiple functional groups?

When naming organic compounds with multiple functional groups, the functional groups are listed in alphabetical order and the prefixes "di-", "tri-", etc. are added to indicate the number of each functional group present. The main chain of the molecule is determined by the functional group with the highest priority, according to the IUPAC rules.

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