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yogi said:Originally Posted by ZapperZ
"Want more? Look at the isotope effect and its effect on the index of refraction! I can keep the same material, but increase the mass of the ions. This changes nothing on the field inside the material - you change nothing with regards to the charge of the atoms. Yet, this changes the index of refraction of the material."
Ah but it does - the electric field of the photon interacts with the electric field of the of the electrons in the outer shells - the electrons are bound by the nucleus - there is an inertial reaction - the inertial reaction depends upon the mass of the isotope. The heavier isotope will be displaced less so the inertial reaction acting back upon the photon will be greater - therefore it will be slowed to a greater extent
But this is the PHONON effect, NOT a "field" effect. The field remains the SAME. I didn't change the nuclear charge nor the number of electrons. All I did was change the ionic MASS. Phonons are normal mode vibrations of the lattice. The optical mode depends on the displacement of the ions. I change nothing about the bonding strength, only the ions masses. The index of refraction changes because the response time of the ions are now different! The field strength that the photon encounters is still identical from before!
So your argument that it may be due to the matter field affecting the photon is wrong. It IS due to the ability of the lattice to oscillate fast enough to react to the photon - these are PHONONS.
I'd ask you to go look at phonon modes in solids, but I don't think you'd do that either.
Zz.