London Dispersion Force in Molecular vs. Ionic Compounds

In summary, London Dispersion Force can exist in both molecular and ionic compounds, but it is more relevant in molecular compounds where it is the main intermolecular attractive force. In ionic compounds, it is the weakest attractive force due to the presence of stronger full positive or full negative charge attractions.
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Homework Statement


Does London Dispersion Force exist only in molecular compounds, or do they also exist in ionic compounds?


Homework Equations


None.


The Attempt at a Solution


I think it exists only in molecular compounds.
 
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  • #2
London forces exist in all atoms and ions. Think about what London forces are (temporary shifts in electron density that create dipoles) this can occur in all particles. However, in ions it would be the weakest attractive force since there are full positive or full negative charge attractions that would be much stronger than these mini temporary dipoles. LF are relevant in molecular compounds (especially non-polar) because that is the main intermolecular attractive force.
 
  • #3


Your response:

The London Dispersion Force exists in both molecular and ionic compounds. This force, also known as van der Waals force, is a type of intermolecular force that arises due to temporary dipoles in molecules or ions. In molecular compounds, these temporary dipoles are caused by fluctuations in electron density, while in ionic compounds, they are caused by the movement of ions. Therefore, the London Dispersion Force is present in both types of compounds.
 

FAQ: London Dispersion Force in Molecular vs. Ionic Compounds

What is London Dispersion Force?

London Dispersion Force is a type of intermolecular force that occurs between non-polar molecules. It is a weak force that results from temporary dipoles formed by the uneven distribution of electrons in a molecule.

How does London Dispersion Force affect the properties of substances?

London Dispersion Force can affect the boiling point, melting point, and viscosity of substances. The stronger the London Dispersion Force, the higher the boiling and melting points will be, and the more viscous the substance will be.

What types of molecules experience London Dispersion Force?

All molecules, regardless of polarity, can experience London Dispersion Force. However, it is typically stronger in larger, more complex molecules with a greater number of electrons.

Can London Dispersion Force be stronger than other intermolecular forces?

No, London Dispersion Force is the weakest of all intermolecular forces. It is always present to some degree, but it is typically overshadowed by other stronger forces such as hydrogen bonding or dipole-dipole interactions.

How does temperature affect London Dispersion Force?

As temperature increases, the strength of London Dispersion Force decreases. This is because higher temperatures cause molecules to move faster, making it more difficult for temporary dipoles to form and for the force to be maintained.

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