Lorentzian line profile of emitted radiation

In summary, the textbook states that the frequency of emitted radiation is no longer monochromatic as it would be for an oscillation with constant amplitude. Instead, it shows a frequency distribution related to the function x(t) by a Fourier transformation- the damped oscillation x(t) can be described as a superposition of monochromatic oscillations exp(i omega t) with slightly different frequencies omega and amplitudes A(omega). The factor of 1/2 should be a factor of 2.
  • #1
MigMRF
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Homework Statement
Explain the derivation of the lorentzian line profile. Use "Laser Spectroscopy 1" By Wolfgang Demtöder pp 76-78 as inspiration
Relevant Equations
Fourier transform, inverse fourier transform, solution to harmonic oscilator.
First of all i tried to follow the textbook. Here they start of by modelling the atom as an harmonic oscilator:
1672957326637.png

Then they find the solution as:
1672957502722.png

They neglect the second term as omega_0 >> gamma which also makes good sense so they end up with:
1672957579050.png

So far so good. After this they state the following:
"
Because the amplitude x.t/ of the oscillation decreases gradually, the frequency of
the emitted radiation is no longer monochromatic as it would be for an oscillation
with constant amplitude. Instead, it shows a frequency distribution related to the
function x(t) by a Fourier transformation-
The damped oscillation x(t) can be described as a superposition of monochromatic oscillations exp(i omega t) with slightly different frequencies omega and amplitudes A(omega).
1672957696728.png

I understand that a inverse fourier transform is going on here, so that we get away from the frequency domain. And the term 1/sqrt(2 pi) is the normalization constant, which also makes good sense. But where does the 1/2 factor come from? The integral goes from 0 to infinity, and as the amplitude is a symmetric function i would expect that we'd have to multiply by two when taking the integral over the half space, not divide.

It's been some hours of trying to figure out what is going on, but without any luck. Hope that some of you can help me out understanding this step in the derivation, as the rest of it seems pretty clear.
 
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  • #2
## A(\omega)=\int x(t) e^{-i \omega t} dt ## apart from a numerical constant. I didn't do the integral just now, but I remember doing it a couple years ago, and I think it should work. Try for ## t>0 ##, because of the damping term.
Use ##\cos(\omega_o t)=(e^{i \omega_o t}+e^{-i \omega_o t})/2 ##.

Edit: and perhaps a minor detail, but it might be a necessary one: ## x(t) ## is real, so you may need to include the negative ## \omega's ##, (and perhaps even negative ## t's ## to get it to work). You might need to write the damping term (the exponent) with a plus sign for ## t<0 ##.
 
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  • #3
MigMRF said:
View attachment 319857
I understand that a inverse fourier transform is going on here, so that we get away from the frequency domain. And the term 1/sqrt(2 pi) is the normalization constant, which also makes good sense. But where does the 1/2 factor come from? The integral goes from 0 to infinity, and as the amplitude is a symmetric function i would expect that we'd have to multiply by two when taking the integral over the half space, not divide.
I agree that the factor of 1/2 should be a factor of 2. But I also think that it should be specified that the real part of the right-hand side should be taken.

From ##A(\omega) = \frac {1}{\sqrt{2\pi}} \int_{-\infty}^\infty{x(t)e^{-i\omega t}} dt## and the fact that ##x(t)## is real, we must have ##A^*(\omega) = A(-\omega)##. So,

$$x(t) = \frac {1}{\sqrt{2\pi}} \int_{-\infty}^\infty{A(\omega)e^{i\omega t}} d\omega $$
$$= \frac {1}{\sqrt{2\pi}} \left(\int_{-\infty}^0{A(\omega)e^{i\omega t}} d\omega + \int_{0}^{\infty}{A(\omega)e^{i\omega t}} d\omega \right)$$
$$= \frac {1}{\sqrt{2\pi}} \left(\int_{0}^{\infty}{A(-\omega)e^{-i\omega t}} d\omega + \int_{0}^{\infty}{A(\omega)e^{i\omega t}} d\omega \right)$$
$$= \frac {1}{\sqrt{2\pi}} \left(\int_{0}^{\infty}{A^*(\omega)e^{-i\omega t}} d\omega + \int_{0}^{\infty}{A(\omega)e^{i\omega t}} d\omega \right)$$
$$= \frac {1}{\sqrt{2\pi}} \left(\int_{0}^{\infty}{A(\omega)e^{i\omega t}} d\omega +CC \right)$$
$$= \frac {2}{\sqrt{2\pi}} Re\left[ \int_{0}^{\infty}{A(\omega)e^{i\omega t}} d\omega \right]$$
 
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FAQ: Lorentzian line profile of emitted radiation

What is a Lorentzian line profile?

A Lorentzian line profile describes the shape of spectral lines emitted by atoms or molecules, characterized by a specific mathematical function. It is defined by its full width at half maximum (FWHM) and is used to represent the broadening of spectral lines due to various physical processes like natural broadening, collisional broadening, and Doppler broadening.

Why is the Lorentzian line profile important in spectroscopy?

The Lorentzian line profile is crucial in spectroscopy because it helps in accurately modeling and analyzing the spectral lines observed in experiments. This profile aids in understanding the underlying physical processes affecting the emission or absorption of radiation, such as interactions with other particles and intrinsic properties of the emitting or absorbing species.

How is the Lorentzian line profile mathematically defined?

The Lorentzian line profile is mathematically defined by the function \( L(\nu) = \frac{1}{\pi} \frac{\gamma/2}{(\nu - \nu_0)^2 + (\gamma/2)^2} \), where \( \nu \) is the frequency, \( \nu_0 \) is the central frequency of the line, and \( \gamma \) is the full width at half maximum (FWHM). This function describes the distribution of intensity around the central frequency.

What physical processes contribute to the Lorentzian line shape?

The Lorentzian line shape primarily arises from natural broadening and collisional broadening. Natural broadening is due to the finite lifetime of excited states, leading to an uncertainty in energy levels. Collisional broadening occurs due to interactions between particles, which perturb the energy levels and cause additional broadening of the spectral lines.

How does the Lorentzian line profile compare to the Gaussian line profile?

The Lorentzian line profile has longer tails compared to the Gaussian line profile, meaning it decreases more slowly as one moves away from the central frequency. The Gaussian profile, characterized by a bell-shaped curve, is typically associated with Doppler broadening due to thermal motion of particles. In many cases, the observed line shape can be a convolution of both Lorentzian and Gaussian profiles, known as a Voigt profile.

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