'magnitude (in kJ/mol) of energy barriers to rotation from anti to gauche'

In summary, the conversation is discussing the concept of energy barriers to rotation between two carbons from the anti to gauche conformer. The question is asking for the difference in energy between these two conformers, but the answer clarifies that the barrier to rotation is not related to the energy of the individual conformers. The conversation also provides a resource for further reading on this topic.
  • #1
Iwantttt
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Homework Statement




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The Attempt at a Solution



Does 'magnitude (in kJ/mol) of energy barriers to rotation from anti to gauche' mean the difference in energy?
This question is asking for the magnitude of energy barriers to rotation about the bond between two carbons from anti to gauche. Do I just subtract gauche energy from anti?
 
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  • #2
Iwantttt said:

Homework Statement




Homework Equations



The Attempt at a Solution



Does 'magnitude (in kJ/mol) of energy barriers to rotation from anti to gauche' mean the difference in energy?
This question is asking for the magnitude of energy barriers to rotation about the bond between two carbons from anti to gauche. Do I just subtract gauche energy from anti?

What is the difference between the two conformers? Use actual values only if you are provided with them.
 
  • #3
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FAQ: 'magnitude (in kJ/mol) of energy barriers to rotation from anti to gauche'

1. What is the meaning of "magnitude of energy barriers to rotation" in terms of anti to gauche conformations?

The magnitude of energy barriers to rotation refers to the amount of energy required to overcome the rotational barrier between the anti and gauche conformations. In other words, it represents the energy difference between the two conformations.

2. How is the magnitude of energy barriers to rotation measured in kJ/mol?

The magnitude of energy barriers to rotation is typically measured in units of kilojoules per mole (kJ/mol). This unit is commonly used in chemistry to express the energy changes associated with chemical reactions and molecular processes.

3. Why is the magnitude of energy barriers to rotation important in chemistry?

The magnitude of energy barriers to rotation is important in chemistry because it directly affects the stability and reactivity of molecules. Higher energy barriers make it more difficult for molecules to undergo conformational changes, which can impact their physical and chemical properties.

4. How does the magnitude of energy barriers to rotation affect the rate of chemical reactions?

The magnitude of energy barriers to rotation can significantly influence the rate of chemical reactions. Higher energy barriers mean that more energy is required for molecules to overcome the barrier and react, resulting in a slower reaction rate. Lower energy barriers, on the other hand, make it easier for molecules to undergo conformational changes and react, leading to a faster reaction rate.

5. How do external factors such as temperature and solvent polarity affect the magnitude of energy barriers to rotation?

External factors such as temperature and solvent polarity can affect the magnitude of energy barriers to rotation. Generally, higher temperatures and more polar solvents can decrease the energy barriers and make it easier for molecules to undergo conformational changes. This can lead to changes in the stability and reactivity of molecules, which can have important implications in various chemical processes.

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