Mass Spec Problem Accelerating potential difference ΔV is required to detect N2+?

In summary: The conversation also included equations for calculating the required accelerating potential difference to detect N2+. However, the attempt at a solution resulted in an incorrect answer and the person is seeking guidance for an alternative solution.
  • #1
Tina20
38
0

Homework Statement



The image below shows a mass spectrometer, an analytical instrument used to identify the various molecules in a sample by measuring their charge-to-mass ratio e/m. The sample is ionized, the positive ions are accelerated (starting from rest) through a potential difference ΔV, and they then enter a region of uniform magnetic field. The field bends the ions into circular trajectories, but after just half a circle they either strike the wall or pass through a small opening to a detector. As the accelerating voltage is slowly increased, different ions reach the detector and are measured. Typical design values are a magnetic field strength B=0.243 T and a spacing between the entrance and exit holes d=7.30 cm. What accelerating potential difference ΔV is required to detect N2+?

Homework Equations



f=qB/2(pi)m

f=frequency
m=mass of N2+ = 2x14.0031u
u=1.661x10-27
therefore mass of N2 = 2x14.0031x1.661x10-27 = 4.6518x10-26

T=1/f

T=v/2(pi)r

1/2mv^2 = qV

The Attempt at a Solution



f=qB/2(pi)m
f=(1.602x10-19)(0.243)/2(pi)(4.6518x10-26)
f=133,188.0004 Hz

T = 1/f
T= 1/133,188.0004 Hz
T=7.50818x10-6s

T=v/2(pi)r
T=v/2(pi)(d/2)
7.50818x10-6s = v/2(pi)(0.0730/2)
v=1.72189x10-6m/s

1/2mv^2 = qV
1/2(4.6518x10-26kg)(1.72189x10-6m/s)^2 = (1.602x10-19C)V
4.304x10-19 = V

The answer is wrong and I have no idea any other way to solve this. Some guidance would be very helpful!

Tina


 
Physics news on Phys.org
  • #2
bump
 

Related to Mass Spec Problem Accelerating potential difference ΔV is required to detect N2+?

1. What is a Mass Spec Problem?

A Mass Spec Problem is a challenge faced by scientists in the field of mass spectrometry, which is a technique used for identifying and analyzing the chemical composition of a substance.

2. What is the purpose of the accelerating potential difference (ΔV) in Mass Spectrometry?

The accelerating potential difference (ΔV) is used to accelerate charged particles (ions) through an electric field in a mass spectrometer. This allows for the separation and detection of different ion species based on their mass-to-charge ratio.

3. Why is ΔV required specifically for detecting N2+?

N2+ is a diatomic molecule and is relatively stable, meaning it requires a higher accelerating potential difference to be detected compared to other ions. This is because the ionization energy (energy required to remove an electron) for N2+ is higher than other ions.

4. How does the value of ΔV affect the detection of N2+?

The value of ΔV directly affects the kinetic energy of the N2+ ions. A higher ΔV will result in higher kinetic energy, allowing the ions to reach the detector faster and with more intensity. This leads to a better signal and easier detection.

5. Are there any other factors that can affect the detection of N2+?

Yes, there are other factors that can affect the detection of N2+, such as the sample concentration, ionization efficiency, and instrument sensitivity. These factors should be optimized along with the accelerating potential difference to ensure accurate and reliable detection of N2+ ions.

Similar threads

  • Introductory Physics Homework Help
Replies
8
Views
458
  • Introductory Physics Homework Help
Replies
4
Views
5K
  • Introductory Physics Homework Help
Replies
5
Views
323
  • Introductory Physics Homework Help
Replies
6
Views
3K
  • Introductory Physics Homework Help
2
Replies
42
Views
3K
  • Introductory Physics Homework Help
Replies
3
Views
863
  • Introductory Physics Homework Help
Replies
2
Views
1K
  • Introductory Physics Homework Help
Replies
10
Views
1K
  • Introductory Physics Homework Help
Replies
2
Views
2K
  • Introductory Physics Homework Help
Replies
6
Views
1K
Back
Top