Matter Waves and Electromagnetic Waves

[kith]

You stated above the theory is silent what is the electron in the atom doing when not observed. No problem with that.. but can we categorically say that the electron is not moving when not observed that is why it is not emitting electromagnetic wave (as we know moving charge radiate em wave)?

Not categorically. What you say is true in the de Broglie-Bohm interpretation. There, the electron inside the atom is at rest and has an exact position. In the more standard Copenhagen interpretation, it has neither an exact position nor an exact momentum/velocity. You cannot say that it is at rest because this would require an exact velocity of zero.

 

[Edward Wij]

Not categorically. What you say is true in the de Broglie-Bohm interpretation. There, the electron inside the atom is at rest and has an exact position. In the more standard Copenhagen interpretation, it has neither an exact position nor an exact momentum/velocity. You cannot say that it is at rest because this would require an exact velocity of zero.

If the electron is at rest in the de Broglie-Bohm interpretation, why doesn't it fall down to the nucleus?
In Copenhagen, are you saying it is moving yet with no exact position and no exact momentum/velocity, but won't this cause it to sporadically radiate em wave?

 

[kith]

If the electron is at rest in the de Broglie-Bohm interpretation, why doesn't it fall down to the nucleus? In Copenhagen, are you saying it is moving yet with no exact position and no exact momentum/velocity, but won't this cause it to sporadically radiate em wave?

Your ideas that the electron should fall down to the nucleus or radiate are based on classical electromagnetism. Maybe there are answers which conform better to this intuition but in the end, it boils down to the fact that classical electromagnetism is wrong and that you have to use a quantum description for both the electron and the electromagnetic field.

One thing is that a electron in the ground state can't lose energy by radiating. If it gets into a state where its position is constrained to a volume smaller than that of the ground state, the uncertainty in momentum increases such that the energy of the electron is bigger than in the ground state. The existence of the ground state can thus be viewed as a direct consequence of the Heisenberg uncertainty principle.

My advice is to learn at least the basic maths of QM in order to see such things for yourself.

 

[bhobba]

You stated above the theory is silent what is the electron in the atom doing when not observed. No problem with that.. but can we categorically say that the electron is not moving when not observed that is why it is not emitting electromagnetic wave (as we know moving charge radiate em wave)?

Of course not - that's what silent means.

In fact Bohmian Mechanics says it has a well defined position and momentum when not observed.

Thanks
Bill

 

[bhobba]

If the electron is at rest in the de Broglie-Bohm interpretation, why doesn't it fall down to the nucleus?

Because its guided by a potential that prevents that.

In Copenhagen, are you saying it is moving yet with no exact position and no exact momentum/velocity, but won't this cause it to sporadically radiate em wave?

Its silent. That means it says nothing, it could be doing all sorts of things, dancing a jig, taking a trip to Mars and back, it doesn't matter, the interpretation doesn't worry about it..

Thanks
Bill

 

[Edward Wij]

Because its guided by a potential that prevents that.
Its silent. That means it says nothing, it could be doing all sorts of things, dancing a jig, taking a trip to Mars and back, it doesn't matter, the interpretation doesn't worry about it..

Thanks
Bill

Perhaps it is better or easier to just think or imagine the electron doesn't exist as particle in between measurement.. and you just have the matter wave (or wave function) existing in the orbital... is it not incorrect to think this way?

 

[bhobba]

Perhaps it is better or easier to just think or imagine the electron doesn't exist as particle in between measurement.. and you just have the matter wave (or wave function) existing in the orbital... is it not incorrect to think this way?

I tend to think that way - its perfectly OK.

Note though the wave-function is not necessarily real.

Thanks
Bill

 

[Edward Wij]

I tend to think that way - its perfectly OK.

Note though the wave-function is not necessarily real.

Thanks
Bill

But if you have to think of the electron as not existing when not measured (or interacted), then the wave function has to be real or else the atoms would just fall apart. I can't imagine the electron not existing and yet the wave function not existing in the atom either... can you? think of this deeply...

 

[bhobba]

But if you have to think of the electron as not existing when not measured (or interacted), then the wave function has to be real or else the atoms would just fall apart..

That doesn't follow. You a making all sorts of tacit assumptions that may or may not be true. In fact in atoms the electrons are entangled with the nucleus - we simply model them as separate to get a mathematical handle on the situation.

Thanks
Bill

 

[vanhees71]

If you have an atom, e.g., prepared to be at rest in your (inertial) reference frame, this means that its center of mass is not moving but that the nucleus and the electron are moving around each other (taken the average positions of these "particles" as their position). You don't need esoterics for this but just quantum theory in the minimal interpretation.

Now to see, what's about radiation emitted from the atom you have to work in full QED, i.e., you have to consider the system of the nucleus, the electrons, and the quantized radiation field. Provided the atom is isolated from its environment (FAPP), then it does not radiate if and only if its in the ground state. All other bound states of the perturbative treatment, where the interaction with the em. radiation field is neglected are in fact instable when the coupling to the radiation field is taken into account. The atom will rearrange itself in the ground state emitting one or more photons in this process. The photons have a small but finite width, which is inverse to the mean lifetime of the excited states.

Of course, it's not to be confused with classical bremsstrahlung from the charged particles within the atom. This phenomenon of the stability of atoms (in the strict sense in the ground state) cannot be understood in classical terms and this was one of the facts that lead to the discovery of quantum theory in 1925/26.

Bohrs model of 1911/12 and Sommerfeld's extension was an important step towards this discovery, but it's in almost all aspects wrong, even qualitatively. There are no "Bohr orbits", and consequently there's no necessity ad-hoc assumption about "orbits, where the electron doesn't rotate". The only way to understand the atom is quantum theory. You can go quite far with non-relativistic quantum theory in the semiclassical limit (i.e., treating the em. field as a classical Coulomb potential rather than the full QED treatment, and this can be proven from QED; see, e.g., the excellent QED treatment of the hydrogen atom in Weinberg's Quantum Theory of Fields, vol. 1).

 

[TrickyDicky]

My astonishment is mainly about pedagogics: the popularity of the double slit makes it seem that it is a standard case of quantum behavior. Yet almost no sources bother to connect it with the full machinery of QM, nor with the well-understood situation in classical optics.

I shared the astonishment, and then I realize that most depictions of the double slit experiment, not only in pop-sci but in many QM textbooks, use a highly distorted description and interpretation of the experiment. Maybe the intention is pedagogical simplification but it seems to be at the cost of seriously deviating from QM. And this trend is followed by many papers concentrating on "wich path" variants , "delayed choices" and "quantum erasers" experiments, they all seem to follow the naive introduction picture and extend a basic misunderstanding about QM.

They all rely on a very old and wrong particle-wave duality conception in which wavefunctions are either behaving as classical waves or classical particles but never at the same time(complementarity),when one doesn't know which way the "classical particle"(since only classical particles have trajectories) traveled they'd be behaving as classical waves and you get classical superposition interference pattern, but if you manage to assign which slit it went thru it obviosly is behaving as a classical particle and you get a pattern compatible with what you'd obtain if you were shooting ping-pog balls thru two holes. This conception first fails to acknowledge the difference between classical and quantum superposition and second fails to abandon the concept of electrons(or any other fields) as classical particles from the moment it considers it can have a classical trajectory and it can be determined which one it is.
All this made sense in the first years of QM but not now.
IOW the simplified versión treats the wave function in the double-slit as a pure state with two possibilities, wave or particle, when in fact there is degeneracy and one can set up the experiment in different ways wrt the relative phase so that interference patterns are more or less evident in the screen. I guess not many people tries the rigorous treatment of the experiment because most are comfortable with the old-style Copenhagen picture of collapse and complementarity.