Maxwell-Boltzmann Distribution function and equipartition theorem

In summary, the gas of electrons constrained to a two-dimensional surface has an expected average kinetic energy given by the equipartition theorem, which reduces to only two velocity terms x and y. For T = 293K, the speed would correspond to a simple rearrangement and calculation. The equivalent of the Maxwell-Boltzmann distribution for this gas is given by p(v) = Cve^{-\frac{mv^{2}}{kT}}, where C can be defined using the integral \int^{\infty}_{0} dvp(v)=N. However, further progress requires a simple substitution, such as u=v^2.
  • #1
redz
3
0

Homework Statement



A gas of electrons is contrained to lie on a two-dimensional surface. I.e. they
have no movement in the z direction but may move freely in the x and y.

a) From the equipartition theorem what is the expected average kinetic energy
as a function of T?

b) For T = 293K what speed would this correspond to?

c) The equivalent of the Maxwell-Boltzman distribution for a two-dimensional
gas is
[tex]p(v) = Cve^{-\frac{mv^{2}}{kT}}[/tex]

Define C such that,
[tex]\int^{\infty}_{0} dvp(v)=N[/tex]

The Attempt at a Solution



a) As the particles are able to move in only two dimensions the equipartition theorem reduces to only have two velocity terms x and y. therefore;
[tex]E_{k}=\frac{1}{2}m(v^{2}_{x}+v^{2}_{y})[/tex]
Where Ek is kinetic energy

This would mean that the total kinetic energy in terms of T would be

[tex]E_{k}=kT[/tex]
Would this be correct?

Part b) will be a simple rearrangement and calculation. no real problems there

c) I have rearranged the integration to;
[tex]C\int^{\infty}_{0}ve^{-\frac{m}{kT}v^{2}} dv=N[/tex]

But have been unable to process further. I think it is supposed to be a standard integral of some sort but have no real clue how to progress
 
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  • #2
a) Yes. Each quadratic term in the energy contributes 1/2 kT to the average energy.

c) It's a simple substitution. Try something like [tex]u=v^2[/tex].
 
  • #3
further



Your approach to part a) and b) seems correct. The average kinetic energy for a two-dimensional gas of electrons would indeed be given by E_{k}=kT, and for T=293K, this corresponds to a speed of 1.38 x 10^5 m/s.

For part c), you are on the right track. The integral you have written is a standard integral known as the Gaussian integral. You can solve it by using the substitution u=v^2 and then using the standard form of the Gaussian integral, which is given by:

\int^{\infty}_{0} e^{-au^2} du = \frac{\sqrt{\pi}}{2a}

Substituting back for v, you should get:

C\frac{\sqrt{\pi}}{2}\frac{1}{\left(\frac{m}{2kT}\right)^{1/2}}=N

Solving for C, you should get:

C=\frac{2N}{\sqrt{\pi}}\left(\frac{m}{2kT}\right)^{1/2}

This is the value of C that satisfies the given condition. I hope this helps!
 

Related to Maxwell-Boltzmann Distribution function and equipartition theorem

1. What is the Maxwell-Boltzmann distribution function?

The Maxwell-Boltzmann distribution function is a mathematical expression that describes the probability of finding a particle with a certain velocity in a gas or liquid at a given temperature. It is named after James Clerk Maxwell and Ludwig Boltzmann, who independently developed the concept in the late 19th century.

2. What is the relationship between the Maxwell-Boltzmann distribution and temperature?

The Maxwell-Boltzmann distribution is directly proportional to temperature. This means that as temperature increases, the distribution shifts towards higher velocities, indicating a greater number of particles with higher energies. Similarly, as temperature decreases, the distribution shifts towards lower velocities, indicating a greater number of particles with lower energies.

3. What is the significance of the equipartition theorem in the Maxwell-Boltzmann distribution?

The equipartition theorem states that in thermal equilibrium, all particles in a system will have equal average energies. In the context of the Maxwell-Boltzmann distribution, this means that at a given temperature, the average energy of all particles will be the same, regardless of their mass or the type of gas or liquid they are in.

4. How does the Maxwell-Boltzmann distribution differ from the Boltzmann distribution?

The Maxwell-Boltzmann distribution is a specific case of the more general Boltzmann distribution. The Maxwell-Boltzmann distribution is used for classical particles, such as gas molecules, while the Boltzmann distribution is used for both classical and quantum particles. The Maxwell-Boltzmann distribution also assumes that all particles have the same mass, while the Boltzmann distribution takes into account particles with different masses.

5. What is the practical application of the Maxwell-Boltzmann distribution?

The Maxwell-Boltzmann distribution is used in various fields of science and engineering, such as thermodynamics, statistical mechanics, and fluid dynamics, to model the behavior of particles in a gas or liquid. It is also used in the design and optimization of devices such as heat exchangers, gas turbines, and refrigeration systems.

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