Mean Free Path: Definition, Impact of Size & Density

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In summary, the mean free path is defined as the average distance traveled by a particle in a container before colliding with another particle. It decreases with increasing size and density of molecules, as well as with increasing temperature of the gas. This is due to more frequent collisions occurring in these scenarios. The definition of mean free path is the correct statement, but it is also important to consider the formula and how different factors affect it when answering this question.
  • #1
lando45
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My teacher has set me this question:

Which of the following statements about the mean free path is correct?

1. The mean free path decreases as the size of the molecules increases.
2. The mean free path increases with the size of the molecules.
3. The mean free path decreases as the density of molecules increases.
4. The mean free path increases with the density of molecules.
5. The mean free path depends on the temperature of the gas.
6. The mean free path is the average distance traveled by a molecule between collisions.
7. The mean free path is the longest distance a particle can travel without colliding.


It doesn't specify how many of the statements are correct, so I tried selecting 1, 5 and 6, but that's incorrect.

I believe the definition of "mean free path" to the be the average distance a particle travels in a container before it collides with another particle.

So I chose 1 because increasing the size of the particles would make collisions more frequent, due to less free space in the container, and therefore a lower mean free path.

I chose 5 because if the temperature of the gas increases, the particles will have more energy, and will therefore move more eratically, causing more collisions, and therefore a low mean free path.

And finally, I chose 6 because this is basically a definition of the term.

Now why didn't I get this question right? Are the 3 options I've chosen correct? Should I be selecting any additional options? Or are the ones I've selected incorrect?
 
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  • #2
Have you seen the formula for mean free path? From this can you tell what cause it to increase and decrease.
 
  • #3


I would like to clarify that the correct statements about the mean free path are:

1. The mean free path decreases as the density of molecules increases.
2. The mean free path depends on the temperature of the gas.
3. The mean free path is the average distance traveled by a molecule between collisions.

Option 1 is correct because as the density of molecules increases, there are more collisions happening in a given space, resulting in a shorter mean free path.

Option 2 is also correct because the temperature of a gas affects the speed and energy of its molecules, which in turn affects their movement and likelihood of collisions. A higher temperature can lead to a longer mean free path.

Option 3 is the correct definition of the mean free path. It is the average distance a molecule travels before colliding with another molecule.

Option 4 is incorrect because as the density increases, the mean free path decreases, as explained in option 1.

Option 5 is incorrect because the temperature affects the speed and energy of the molecules, which affects their movement and likelihood of collisions, as explained in option 2.

Option 6 is correct and is the definition of the mean free path.

Option 7 is incorrect because the mean free path is an average and there is no specific limit or maximum distance a particle can travel without colliding. It depends on various factors such as temperature, density, and size of the molecules.
 

FAQ: Mean Free Path: Definition, Impact of Size & Density

What is the definition of mean free path?

The mean free path is the average distance a particle travels in a gas or liquid before it collides with another particle.

How does the size of particles affect mean free path?

The mean free path is inversely proportional to the size of particles. This means that smaller particles have a longer mean free path compared to larger particles.

How does the density of a substance impact mean free path?

The mean free path is directly proportional to the density of a substance. This means that as the density increases, the mean free path decreases. This is because there are more particles in a denser substance, leading to more frequent collisions.

What is the importance of mean free path in understanding gas behavior?

The mean free path is an important concept in understanding the behavior of gases, as it helps explain phenomena such as diffusion and thermal conductivity. It also provides insight into the properties of gases at different pressures and temperatures.

How is mean free path calculated?

The mean free path can be calculated using the following formula: λ = (kT)/(√2πd2p), where λ is the mean free path, k is the Boltzmann constant, T is the temperature, d is the diameter of the particles, and p is the pressure. Alternatively, it can be determined experimentally by measuring the distance traveled by particles before collision.

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