Mixture of ideal gas (a tricky one?)

In summary, to determine the final pressure and entropy change after the inner vessel ruptures, you will need to use the ideal gas equation and the volume ratio of the two vessels. The final pressure is 9365kPa and the entropy change is 0.1671kJ/K.
  • #1
quessy
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0

Homework Statement



ethylene is stored in 5.6 liter spherical vessel at 260degC and 2750 kPa. To protect against explosion the vessel is enclosed in another spherical vessel with volume of 56L and filled with nitrogen at 260degC and 10.1Mpa. The entire assembly is maintained at 260degC in a furnace. The inner vessel raptures/ruptures. Determine the final pressure and the entropy change

Homework Equations



just give me a clue where to start i think i will be able to solve it. but i will appreciate if you answer it.

The Attempt at a Solution



of course i tried to use the ideal gas equation. and i think, from my understanding, rupture means it expands. so correct me if I am wrong. by the way i have the final answers: P=9365kPa and 0.1671kJ/K
 
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  • #2


Hello,

Thank you for your post. It seems like you are on the right track by using the ideal gas equation. The first step would be to determine the initial number of moles of ethylene in the inner vessel. This can be done by using the ideal gas equation, PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the gas constant, and T is temperature. You have all the necessary values except for n, so you can solve for n.

Once you have the initial number of moles of ethylene, you can use the ideal gas equation again to determine the final pressure. However, since the inner vessel has ruptured, the volume will increase and the number of moles will remain the same. So the equation would be P1V1 = P2V2, where P1 and V1 are the initial pressure and volume, and P2 and V2 are the final pressure and volume.

To determine the final volume, you can use the volume ratio of the two vessels (56L/5.6L) to find the final volume of the ethylene. Then you can solve for the final pressure.

As for the entropy change, you can use the equation ΔS = nRln(V2/V1), where ΔS is the change in entropy, n is the number of moles, R is the gas constant, and V2/V1 is the volume ratio. Again, the number of moles remains the same, so you can solve for the entropy change.

I hope this helps give you a starting point. Let me know if you have any further questions. Good luck with your calculations!
 

FAQ: Mixture of ideal gas (a tricky one?)

What is a mixture of ideal gas?

A mixture of ideal gas is a combination of different ideal gases, where each gas behaves independently and does not interact with the others. This means that the properties of the mixture can be predicted using the individual properties of each gas.

How do you determine the properties of a mixture of ideal gas?

The properties of a mixture of ideal gas can be determined using the ideal gas law, which states that the pressure, volume, and temperature of a gas are directly proportional to each other. By knowing the individual properties of each gas, the overall properties of the mixture can be calculated.

Can real gases behave like ideal gases in a mixture?

In some cases, real gases can behave like ideal gases in a mixture, but this is not always the case. Ideal gases do not have any intermolecular forces, while real gases can have attractive or repulsive forces between molecules. Therefore, the behavior of a gas in a mixture depends on its individual properties.

How do you calculate the partial pressures of gases in a mixture?

The partial pressure of a gas in a mixture can be calculated using Dalton's law of partial pressures, which states that the total pressure of a mixture of gases is equal to the sum of the partial pressures of each gas. This can be calculated by multiplying the mole fraction of each gas by the total pressure of the mixture.

What are some real-world applications of mixtures of ideal gas?

Mixtures of ideal gas have many applications in various industries, such as in the production of airbags, where a mixture of nitrogen and oxygen is used to inflate the airbag quickly. They are also used in gas turbines, refrigeration systems, and in the study of atmospheric gases. Additionally, mixtures of ideal gas are commonly used in chemistry experiments and in the development of new materials.

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