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For two non-interacting fermions confined to a 1d box of length L. Construct the antisymmetric wave functions (Slater determinant) and compare ground state energies of two systems, one in the singlet state and the other in the triplet state. For both states, evaluate the probability of find the two particles at the same position. Here's what I have so far...
ψn(x) = √2/L*sin(πnx/L)
En = (h2π2))/2m * (n/L)2
Egrnd = E1 + E1 = 2E1 = (h2/m)(π/L)2
ψgrnd = ψ1(x1)ψ1(x2)*1/√2(σ1↑σ2↓-σ1↓σ2↑)
E1st = E1 + E2 = (5h2/m)(π/L)2
ψ1stsinglet = 1/√2 * ψ1(x1)ψ2(x2)+ψ2(x1)ψ1(x2) * 1/√2(σ1↑σ2↓-σ1↓σ2↑)
ψ1sttriplet = 1/√2 * ψ1(x1)ψ2(x2)-ψ2(x1)ψ1(x2)
For two non-interacting fermions confined to a 1d box of length L. Construct the antisymmetric wave functions (Slater determinant) and compare ground state energies of two systems, one in the singlet state and the other in the triplet state. For both states, evaluate the probability of find the two particles at the same position. Here's what I have so far...
ψn(x) = √2/L*sin(πnx/L)
En = (h2π2))/2m * (n/L)2
Egrnd = E1 + E1 = 2E1 = (h2/m)(π/L)2
ψgrnd = ψ1(x1)ψ1(x2)*1/√2(σ1↑σ2↓-σ1↓σ2↑)
E1st = E1 + E2 = (5h2/m)(π/L)2
ψ1stsinglet = 1/√2 * ψ1(x1)ψ2(x2)+ψ2(x1)ψ1(x2) * 1/√2(σ1↑σ2↓-σ1↓σ2↑)
ψ1sttriplet = 1/√2 * ψ1(x1)ψ2(x2)-ψ2(x1)ψ1(x2)
- σ1↑σ2↑
- 1/√2(σ1↑σ2↓+σ1↓σ2↑)
- σ1↓σ2↓
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