Normal modes of diatomic linear chain

In summary, the dispersion relation of a diatomic linear chain will reduce to the monoatomic one when the coupling constants are equal, and the spectrum displays two branches - the acoustic mode and the optical mode. The acoustic mode is characterized by the negative sign in the dispersion relation and follows the relationship \omega = c k for small k values. The optical mode, on the other hand, is characterized by the positive sign and is often excited by light in real materials. It does not contribute to the specific heat at low temperatures and is not part of the low lying spectrum.
  • #1
goulio
15
0
Hello,

I'm preparing for my condensed matter exam and I'm trying to solve problem 3a) of chapter 22 in Ashcroft & Mermin. The problem is basically to prove that the dispersion relation of a diatomic linear chain will reduce to the monoatomic one when the coupling constants are equal, [itex]K=G=K_0[/itex]. Starting off with equation (22.37)
[tex]
\omega^2 = \frac{K+G}{M} \pm \frac{1}{M}\sqrt{K^2 + G^2 + 2KG \cos k a}
[/tex]
I get
[tex]
\omega^2 = \frac{2 K_0}{M}(1 \pm | \cos \[(k a)/2 \] | )
[/tex]
if we take the minus sign (and ignore the absolute value) we get back to the monoatomic result with a lattice constant of [itex]a/2[/itex]. But why would prefer the minus sign and remove the absolute value?

Thanks
 
Last edited:
Physics news on Phys.org
  • #2
You can check that for the relevant values of k, [tex] \cos{(ka/2)} [/tex] is greater than zero hence you can drop the absolute value. The spectrum displays two branches, the branch with the negative sign is called the acoustic mode because for small k the frequency goes like [tex] \omega = c k [/tex]. The other branch, obtained by choosing the plus sign, is called the optical mode because this mode is often excited by light in real materials. The frequency of the optical mode does not vanish as k tends to zero and this mode is not part of the low lying spectrum. In particular, it won't contribute to the specific heat at low temperatures because it can't be thermally excited.
 
Last edited:

FAQ: Normal modes of diatomic linear chain

What are normal modes of diatomic linear chain?

Normal modes of diatomic linear chain refer to the different ways in which a linear chain of two atoms can vibrate. These vibrations are characterized by a specific frequency and amplitude.

How are normal modes of diatomic linear chain calculated?

Normal modes of diatomic linear chain can be calculated using the equations of motion and the principle of superposition. These calculations involve determining the energies and displacements of each atom in the chain.

What is the significance of normal modes of diatomic linear chain?

The normal modes of diatomic linear chain are important in understanding the physical properties of materials, such as thermal conductivity and heat capacity. They also play a role in the study of molecular vibrations in chemistry.

How many normal modes of diatomic linear chain are there?

There are three normal modes of diatomic linear chain: two stretching modes and one bending mode. These modes correspond to the different ways in which the atoms in the chain can oscillate.

How do normal modes of diatomic linear chain affect the behavior of materials?

The normal modes of diatomic linear chain determine the frequency at which a material can vibrate, and therefore affect its thermal and mechanical properties. They also contribute to the overall stability and strength of materials.

Back
Top