Paramagnetic term of the hamiltonian

In summary, the Hamiltonian for a particle in an electromagnetic field can be written as H = 1/2m (p - qA)^2 + q phi. If we take the cross-terms, which correspond to the paramagnetic term, we have H para = -q/2m * (p.A + A.p) = iqh/2m * (\nabla .A + A.\nabla). However, in QM, the A.del term comes in twice, so the final simplified form is iqh/m * A.\nabla, assuming \nabla .A = 0 in Coulomb gauge. This explains why the factor of 1/2 disappears.
  • #1
dd331
4
0
The Hamiltonian for particle in an EM field is

H = 1/2m (p - qA)^2 + q phi

If we take the cross-terms, which corresponds to the paramagnetic term, we have
[tex]
H para = -q/2m * (p.A + A.p )
= iqh/2m * (\nabla .A + A.\nabla)
[/tex]

What I do not understand is how this simplifies into [tex] iqh/m * A.\nabla [/tex]?

assuming that [tex] \nabla .A = 0[/tex] (i.e. Coulomb gauge). Why does the factor of 1/2 disappears? I'm only a first year undergraduate and I'm learning this on my own. I will appreciate it if you give a fuller answer. Thank you.
 
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  • #2
In QM, H is assumed to act on a wave function \psi.
This means that del.A really means del.(A \psi)=(del.A)\psi + (A.del)\psi, so the (A.del) comes in twice.
 
  • #3


The paramagnetic term in the Hamiltonian represents the interaction between the particle's momentum and the electromagnetic (EM) field. In this case, the EM field is described by the vector potential, A, and the scalar potential, phi. The cross-terms in the Hamiltonian, H para, involve the dot product between the momentum, p, and the vector potential, A. This can be rewritten as p.A = A.p, as dot products are commutative.

Now, in order to simplify this further, we need to consider the Coulomb gauge, where the divergence of the vector potential is equal to zero, \nabla .A = 0. This means that the vector potential only has transverse components and does not have any longitudinal components. In this case, the dot product of A with the gradient operator, \nabla, will also be equal to zero, A.\nabla = 0.

Therefore, in the Coulomb gauge, the paramagnetic term simplifies to H para = iqh/2m * (\nabla .A + A.\nabla) = iqh/2m * (0 + 0) = 0. This is why the factor of 1/2 disappears, as it is multiplied by zero.

In summary, the factor of 1/2 disappears in the Coulomb gauge because the dot product between the momentum and the vector potential is equal to zero. This simplification only holds in the Coulomb gauge, as in other gauges the dot product may not be equal to zero and the factor of 1/2 would not disappear. I hope this explanation helps you understand the concept better. Keep up the good work in your studies!
 

FAQ: Paramagnetic term of the hamiltonian

What is the paramagnetic term of the Hamiltonian?

The paramagnetic term of the Hamiltonian is a mathematical expression that describes the energy associated with the interaction between a magnetic field and the magnetic moment of a particle or system. It is one of the terms in the Hamiltonian, which is a mathematical operator used to describe the total energy of a system.

How does the paramagnetic term affect the energy levels of a system?

The paramagnetic term of the Hamiltonian can increase or decrease the energy levels of a system, depending on the strength and direction of the magnetic field. If the magnetic field is aligned with the magnetic moment of the system, the energy levels will increase. If the magnetic field is opposite to the magnetic moment, the energy levels will decrease.

What types of systems exhibit a paramagnetic term in their Hamiltonian?

Any system that has a magnetic moment, such as atoms, molecules, or even larger particles, can exhibit a paramagnetic term in their Hamiltonian. This term is particularly important in systems with unpaired electrons, as they have a non-zero magnetic moment and can interact with an external magnetic field.

How does the paramagnetic term contribute to the magnetic properties of materials?

The paramagnetic term in the Hamiltonian plays a crucial role in determining the magnetic properties of materials. It describes the energy required to align the magnetic moments of individual particles in a material, which ultimately affects the overall magnetic behavior of the material.

Can the paramagnetic term be manipulated to control the magnetic properties of materials?

Yes, the paramagnetic term can be manipulated by changing the strength or direction of the external magnetic field. This can be used to control the magnetic properties of materials, such as their magnetic susceptibility and magnetization, which has practical applications in various fields, including materials science, electronics, and biomedical engineering.

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