Particle in 3D Box: Wavefunctions and Energies

In summary, the conversation discusses solving for the wavefunctions and energies of a particle constrained by walls in a cubic box. The solutions can be found at the provided links and the boundary conditions of the problem involve the wave function being zero at the walls. The conversation also mentions using intuition to determine the values of constants and asks for clarification on the boundary conditions. The solution involves starting with one dimension and showing that the wavefunction must be in the form of sine of a constant multiplied by the position variable.
  • #1
carllacan
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3

Homework Statement



A particle is constrained by walls that form a cubic box. Obtain the wavecuntions and the energies.

Homework Equations



This is a summary of the solutions: http://quantummechanics.ucsd.edu/ph130a/130_notes/node202.html
Here there is also some info: http://en.wikipedia.org/wiki/Particle_in_a_box#Higher-dimensional_boxes

The Attempt at a Solution



I've managed to obtain the correct solution, but I didn't know how to state the boundary conditions and I had to decide the values of the constants using "intuition".

Could you explain me how would the BC look like in this scenario?

Thank you for your time.
 
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  • #2
Wave function is zero at the walls.
 
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  • #3
Start off with one dimension, with the boundary condition dauto mentioned, show that ##k = \frac{n \pi}{L}## and the wavefunction must be of the form ##sin (kx)##.
 
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FAQ: Particle in 3D Box: Wavefunctions and Energies

What is a "Particle in 3D Box"?

A "Particle in 3D Box" is a theoretical model used in quantum mechanics to describe the behavior of a particle confined within a three-dimensional space, such as a box. It is often used to study the properties of electrons in atoms or molecules.

What are wavefunctions and energies in the context of "Particle in 3D Box"?

Wavefunctions refer to the mathematical functions that describe the probability of finding a particle at a certain position within the 3D box. Energies refer to the different energy levels that a particle can have within the box, which are determined by the size and shape of the box.

How are the wavefunctions and energies of a "Particle in 3D Box" calculated?

The wavefunctions and energies of a "Particle in 3D Box" are calculated using the Schrödinger equation, which is a fundamental equation in quantum mechanics that describes the behavior of particles in a given potential energy field. The solution to this equation gives the wavefunctions and energies of the particle in the 3D box.

What is the significance of studying "Particle in 3D Box"?

Studying the "Particle in 3D Box" model allows us to better understand the behavior of particles in confined spaces, which has practical applications in fields such as materials science, nanotechnology, and electronics. It also helps us understand the fundamental principles of quantum mechanics and how particles behave at the smallest scales.

Are there any limitations to the "Particle in 3D Box" model?

Yes, the "Particle in 3D Box" model is a simplified representation of real-world systems and has limitations. For example, it assumes that the walls of the box are perfectly rigid and that the particle does not interact with its surroundings. In reality, particles may interact with other particles or the walls of the box, which can influence their behavior.

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