Particle in a Box: Solving for Acceptable Wave Function with Boundary Conditions

In summary, the conversation discusses the acceptability of a proposed wave function \Psi = (2/L)^{1/2} (sin (\pix/L) in the context of the infinite square well problem. The wave function must satisfy the boundary conditions and be normalized. The conversation concludes that the proposed wave function does not satisfy the boundary conditions, and therefore cannot be accepted as a solution.
  • #1
thomashpotato
3
0

Homework Statement



V(x) = 0 if [itex]\frac{-L}{2}[/itex]<x<[itex]\frac{L}{2}[/itex] and [itex]\infty[/itex] otherwise.

Is the wave function [itex]\Psi[/itex] = (2/L)[itex]^{1/2}[/itex] (sin ([itex]\pi[/itex]x/L) an acceptable solution to this? Explain

Homework Equations



H[itex]\Psi[/itex]= E[itex]\Psi[/itex] , normalization: 1 = [itex]\int[/itex] wavefunction^{2}dx

The Attempt at a Solution



My logic is that I have to come up with a wave function that satisfy the boundary condition. Therefore [itex]\Psi[/itex] (x= [itex]\frac{-L}{2}[/itex]) = [itex]\Psi[/itex] (x = [itex]\frac{L}{2}[/itex]) = 0

My initial answer was that it's not because I was thinking that the wavefunction itself has to be A[/itex]cosine(bx), where b=2n[itex]\pi[/itex]/L. n = 1/4, 3/4 , 5/4 ...

I am not quite sure if that's correct. Also when I try to calculate the normalization factor (A), it turns out to be 1 = [itex]\frac{A^{2}L}{2}[/itex] + [itex]\frac{A^{2}L}{n\pi}[/itex] sin ([itex]\frac{n\pi}{2}[/itex])
 
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  • #2
thomashpotato said:

Homework Statement



V(x) = 0 if [itex]\frac{-L}{2}[/itex]<x<[itex]\frac{L}{2}[/itex] and [itex]\infty[/itex] otherwise.

Is the wave function [itex]\Psi[/itex] = (2/L)[itex]^{1/2}[/itex] (sin ([itex]\pi[/itex]x/L) an acceptable solution to this? Explain

Homework Equations



H[itex]\Psi[/itex]= E[itex]\Psi[/itex] , normalization: 1 = [itex]\int[/itex] wavefunction^{2}dx

The Attempt at a Solution



My logic is that I have to come up with a wave function that satisfy the boundary condition. Therefore [itex]\Psi[/itex] (x= [itex]\frac{-L}{2}[/itex]) = [itex]\Psi[/itex] (x = [itex]\frac{L}{2}[/itex]) = 0
This is right. Does the proposed wave function satisfy these conditions?

My initial answer was that it's not because I was thinking that the wavefunction itself has to be A[/itex]cosine(bx), where b=2n[itex]\pi[/itex]/L. n = 1/4, 3/4 , 5/4 ...
You'll actually get both sine and cosine solutions if you solve the infinite square well problem completely, so just because this wave function has a sine in it isn't reason enough to exclude it.

I am not quite sure if that's correct. Also when I try to calculate the normalization factor (A), it turns out to be 1 = [itex]\frac{A^{2}L}{2}[/itex] + [itex]\frac{A^{2}L}{n\pi}[/itex] sin ([itex]\frac{n\pi}{2}[/itex])
 
  • #3
I think your reasoning is correct. The wave function doesn't vanish at the boundaries. So it's not good. I wouldn't worry about whether the normalization is correct if the boundary conditions aren't correct.
 

FAQ: Particle in a Box: Solving for Acceptable Wave Function with Boundary Conditions

What is a "Particle in a Box"?

A "Particle in a Box" is a theoretical model used in quantum mechanics to describe the behavior of a particle confined to a finite space. The box represents the boundaries or limits of the particle's movement, and the particle is assumed to have no potential energy outside of the box.

What are the boundary conditions for a "Particle in a Box"?

The boundary conditions for a "Particle in a Box" are that the wave function of the particle must be continuous and finite at the boundaries of the box. This means that the wave function cannot have any sudden or infinite changes at the boundaries.

How do you solve for an acceptable wave function in a "Particle in a Box"?

To solve for an acceptable wave function in a "Particle in a Box", you must use the Schrödinger equation and apply the boundary conditions to find a solution. This typically involves using mathematical techniques such as separation of variables and applying the normalization condition to ensure the wave function is properly scaled.

What is the significance of solving for an acceptable wave function in a "Particle in a Box"?

Solving for an acceptable wave function in a "Particle in a Box" allows us to understand the behavior of a quantum particle within a confined space. It also provides insights into the energy levels and probabilities of the particle's position within the box, which can have important implications in various fields such as solid-state physics and quantum computing.

Can the "Particle in a Box" model be applied to real-world systems?

While the "Particle in a Box" model is a simplification of real-world systems, it can still provide useful insights and predictions. In fact, the model has been successfully applied in various areas such as the study of atoms in a molecule and the behavior of electrons in a semiconductor. However, it is important to note that the model does have its limitations and may not fully capture the complexities of real-world systems.

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