- #1
andre220
- 75
- 1
Homework Statement
Prove the relationship
$$\left(\frac{\partial H}{\partial\lambda}\right)_{nn} = \frac{\partial E_{nn}}{\partial\lambda},$$
where ##\lambda## is a parameter in the Hamiltonian. Using this relationship, show that the average force exerted by a particle in an infinitely deep potential well ##(0\le x\le a)##, on the right "wall" can be written as $$\langle F_\textrm{right}\rangle_n = \frac{\partial E_n}{\partial a},$$ where ##n## is the energy level. Calculate the force and compare it with the classical expression.
Homework Equations
For the first part: ##\hat{H}_\lambda|\psi_\lambda\rangle = E_\lambda|\psi_\lambda\rangle##
##\langle \psi_\lambda|\psi_\lambda\rangle = 1##
##\frac{d}{d\lambda}\langle \psi_\lambda|\psi_\lambda\rangle = 0##
For the well: ##E_n = \frac{n^2\pi^2\hbar^2}{2ma^2}##
The Attempt at a Solution
Okay so here is what I am thinking for the first part:
$$\begin{eqnarray}
\frac{d E_\lambda}{d\lambda} & = & \frac{d}{d\lambda}\langle\psi_\lambda|\hat{H}_\lambda|\psi_\lambda\rangle \\
& = & \langle \frac{d\psi_\lambda}{d\lambda}|\hat{H}_\lambda|\psi_\lambda\rangle + \langle\psi_\lambda |\hat{H}_\lambda|\frac{d\psi_\lambda}{d\lambda}\rangle + \langle\psi_\lambda|\frac{d\hat{H}_\lambda}{d\lambda}|\psi_\lambda\rangle \\
& = & E_\lambda \langle\frac{d\psi_\lambda}{d\lambda}|\psi_\lambda\rangle + E_\lambda\langle\psi_\lambda|\frac{d\psi_\lambda}{d\lambda}\rangle + \langle\psi_\lambda|\frac{d\hat{H}_\lambda}{d\lambda}|\psi_\lambda\rangle\\
& = & \langle \psi_\lambda |\frac{d\hat{H}_\lambda}{d\lambda}|\psi_\lambda\rangle
\end{eqnarray}$$
I am not sure if this is the correct direction to go but I figured it was worth a try. Any help or comments are appreciated.