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There are many apparent paradoxes in quantum mechanics. Luckily, a careful application of math reveals that all is well. But can you figure out why the following ##7## challenges are not paradoxes?
Rules:
Challenge 1
For a particle in one dimension, the operators of momentum ##P## and position ##Q## satisfy Heisenberg’s canonical commutation relation
[tex][P, Q] = \frac{\hbar}{i} \boldsymbol{1}[/tex]
By taking the trace of this relation, one finds a vanishing result for the left-hand side, ##\text{Tr}[P, Q] = 0##, whereas ##\text{Tr}\left(\frac{\hbar}{i}\boldsymbol{1}\right)\neq 0##. What went wrong?
Challenge 2
Consider wave functions ##\varphi## and ##\psi## which are square integrable on ##\mathbb{R}## and the momentum ##P = \frac{\hbar}{i}\frac{d}{dx}##. Integration by parts yields
[tex]\int_{-\infty}^{+\infty}\overline{\varphi(x)}(P\psi)(x)dx = \int_{-\infty}^{+\infty} \overline{(P\varphi)(x)}\psi(x)dx + \frac{\hbar}{i} [ (\overline{\varphi}\psi)(x)]_{-\infty}^{+\infty}[/tex]
Since ##\varphi## and ##\psi## are square integrable, one usually concludes that these functions vanish for ##x\rightarrow \pm\infty##. Thus, the last term in the previous equation vanishes, which implies that the operator P is Hermitian.
However, the textbooks of mathematics tell us that square integrable functions do, in general, not admit a limit for ##x\rightarrow \pm \infty## and therefore they do not necessarily vanish at infinity. There are even functions which are continuous and square summable on ##\mathbb{R}## without being bounded at infinity: an example of such a function is given by
[tex]f(x) = x^2 e^{-x^8\sin^2x}[/tex]
Can one conclude that the operator P is Hermitian in spite of these facts and if so, why?
Challenge 3
Consider the operators ##P = \frac{\hbar}{i} \frac{d}{dx}## and "##Q = ## multiplication by ##x##" acting acting on wave functions depending on ##x ∈ \mathbb{R}##. Since ##P## and ##Q## are Hermitian operators, the operator
[tex]A = PQ^3 + Q^3P[/tex]
also has this property, because its adjoint is given by
[tex]A^\dagger = (PQ^3 + Q^3P)^\dagger = Q^3P + PQ^3 = A[/tex]
It follows that all eigenvalues of ##A## are real. Nevertheless, one easily verifies that
[tex]Af = \frac{\hbar}{i}f[/tex]
with
[tex]f(x) = \left\{\begin{array}{ll}
\frac{1}{\sqrt{2}} |x|^{-3/2}\text{exp}\left(-\frac{1}{4x^2}\right) & \text{for}~x\neq 0\\
0 & \text{for}~x=0
\end{array}\right.[/tex]
which means that ##A## admits the complex eigenvalue ##\hbar/i##. Note that the function ##f## is infinitely differentiable on ##\mathbb{R}## and that it is square integrable, since
[tex]\int_{-\infty}^{+\infty} |f(x)|^2dx = 2\int_0^{+\infty}|f(x)|^2dx = \int_0^{+\infty} x^{-3} \text{exp}\left(-\frac{1}{2x^2}\right)dx= [\text{exp}(-1/(2x^2))]_0^{+\infty} = 1[/tex]
Where is the error?
Challenge 4
Let us consider a particle confined to the interval ##[0, 1]## and described by a wave function ##\psi## satisfying the boundary conditions ##\psi(0) = 0 = \psi(1)##. Then the momentum operator
[tex]P = \frac{\hbar}{i}\frac{d}{dx}[/tex]
is Hermitian, since the surface term appearing upon integration by parts vanishes:
[tex]\int_0^1 \left(\overline{\varphi}(P\psi) - \overline{(P\varphi)}\psi\right)(x)dx = \frac{\hbar}{i}[(\overline{\varphi}\psi)(x)]_0^1 = 0[/tex]
Since P is Hermitian, its eigenvalues are real. In order to determine the latter, we note that the eigenvalue equation,
[tex](P\psi_p)(x) = p\psi_p(x)[/tex]
is solved by ##\psi_p(x) = c_p \text{exp}\left(\frac{i}{\hbar}px\right)## with ##p\in \mathbb{R}## and ##c_\in \mathbb{C}\setminus\{0\}##. The boundary condition ##\psi_p(0) = 0## now implies ##\psi_p = 0##, therefore ##P## does not admit any eigenvalues. Nevertheless, the spectrum of ##P## is the entire complex plane and ##P## does not represent an observable. How can one understand these results which seem astonishing?
Challenge 5
If one introduces polar coordinates in the plane or spherical coordinates in space, then the polar angle ##\varphi## and the component ##L_z## of angular momentum are canonically conjugate variables in classical mechanics. In quantum theory, the variable ##\varphi## becomes the operator of "multiplication of the wave function ##\psi(\varphi)## by ##\varphi## " and ##L_z = \frac{\hbar}{i} \frac{\partial}{\partial \varphi}##, which implies the commutation relation
[tex][L_z,\varphi] = \frac{\hbar}{i}\boldsymbol{1}[/tex]
These operators acting on periodic wave functions (i.e. ##\psi(0) = \psi(2\pi)##) are Hermitian. Furthermore, ##L_z## admits a complete system of orthonormal eigenfunctions ##\psi_m## for ##m\in \mathbb{Z}## and
[tex]L_z \psi_m = m\hbar\psi_m~\text{with}~\psi_m(\varphi) = \frac{1}{\sqrt{2\pi}}\text{exp}(im\varphi).[/tex]
By evaluating the average value of the operator ##[L_z,\varphi]## in the state ##\psi_m## and by taking
into account the fact that ##L_z## is Hermitian, one finds that
[tex]\begin{align*}
\frac{\hbar}{i}
& = \left\langle \psi_m, \frac{\hbar}{i}\boldsymbol{1} \psi_m\right\rangle\\
& = \left\langle \psi_m, L_z\varphi \psi_m\right\rangle - \left\langle \psi_m, \varphi L_z\psi_m\right\rangle\\
& = \left\langle L_z^\dagger\psi_m, \varphi \psi_m\right\rangle - m\hbar\left\langle \psi_m, \varphi \psi_m\right\rangle\\
& = (m\hbar - m\hbar)\left\langle \psi_m, \varphi \psi_m\right\rangle\\
& = 0
\end{align*}[/tex]
Where is the problem?
Challenge 6
Let us add a bit to the confusion of the previous example! In 1927, Pauli noted that the
canonical commutation relation implies Heisenberg’s uncertainty relation ##\Delta P \Delta Q\geq \frac{\hbar}{2}## by virtue of the Cauchy-Schwarz inequality. One can derive, in the same way, the uncertainty relation
[tex] \Delta L_z \Delta \varphi\geq \frac{\hbar}{2}[/tex]
The following physical reasoning shows that this inequality cannot be correct. One can always find a state for which ##\Delta L_z < \frac{\hbar}{4\pi}## and then the uncertainty for the angle ##\varphi## has to be larger than ##2\pi##, which does not have any physical sense, since ##\varphi## takes values in the interval ##[0, 2\pi)##. How is this possible?By the way, this example shows that the uncertainty relation ##\Delta A \Delta B\geq \frac{1}{2}|\left\langle [A,B]\right\rangle|## for any two observables ##A## and ##B## (whose derivation can be found in most quantum mechanics texts) is not valid in such a generality.
Challenge 7
Let us consider a particle of mass ##m## in the infinite potential well (for ##a>0##)
[tex]V(x) = \left\{\begin{array}{ll}
0 & \text{if}~|x|\leq a\\
\infty & \text{otherwise}
\end{array}\right.[/tex]
The Hamiltonian for the particle confined to the inside of the well is simply
[tex]H = - \frac{\hbar^2}{2m} \frac{d^2}{dx^2}[/tex]
Let
[tex]\psi(x) = \left\{\begin{array}{ll}
\frac{\sqrt{15}}{4a^{5/2}}(a^2 - x^2) & \text{if}~|x|\leq a\\
0 & \text{otherwise}
\end{array}\right.[/tex]
be the normalized wave function of the particle at a given time. Since
[tex]H^2\psi = \frac{\hbar^4}{4m^2}\frac{d^4}{dx^4}\psi = 0,[/tex]
the average value of the operator ##H^2## in the state ##ψ## vanishes:
[tex]\left\langle H^2\right\rangle_\psi = \left\langle\psi,H^2\psi\right\rangle = \int_{-a}^a\overline{\psi(x)}(H^2\psi)(x)dx = 0[/tex]
This average value can also be determined from the eigenvalues and eigenfunctions of H,
[tex]H\varphi_n = E_n \varphi_n[/tex]
with
[tex]E_n = \frac{\pi^2\hbar^2}{8ma^2} n^2~\text{for}~n=1,2,3,...[/tex]
by applying the formula
[tex]\left\langle H^2\right\rangle_\psi = \sum_{n=1}^{+\infty} E_n^2 p_n[/tex]
with ##p_n = |\left\langle\varphi_n,\psi\right\rangle|^2##.
Proceeding in this way, one definitely does not find a vanishing result, because ##E_n^2>0## and ##0\leq p_n\leq 1##, ##\sum_{n=1}^{\infty} p_n = 1##. In fact, the calculation yields ##\left\langle H^2\right\rangle_\psi = \frac{15\hbar^4}{8m^2a^4}##. Which one of these two results is correct and where does the inconsistency come from?
References
[1] Mathematical surprises and Dirac's formalism in quantum mechanics by François Gieres.
https://arxiv.org/pdf/quant-ph/9907069
Rules:
- Do not look at paper [1] before answering. It contains all the answers in detail. Any other use of outside sources is allowed, but make sure to quote them.
- Give a careful explanation why you think the speciic situation is not a paradox. Use any math/physics you wish.
Challenge 1
For a particle in one dimension, the operators of momentum ##P## and position ##Q## satisfy Heisenberg’s canonical commutation relation
[tex][P, Q] = \frac{\hbar}{i} \boldsymbol{1}[/tex]
By taking the trace of this relation, one finds a vanishing result for the left-hand side, ##\text{Tr}[P, Q] = 0##, whereas ##\text{Tr}\left(\frac{\hbar}{i}\boldsymbol{1}\right)\neq 0##. What went wrong?
Challenge 2
Consider wave functions ##\varphi## and ##\psi## which are square integrable on ##\mathbb{R}## and the momentum ##P = \frac{\hbar}{i}\frac{d}{dx}##. Integration by parts yields
[tex]\int_{-\infty}^{+\infty}\overline{\varphi(x)}(P\psi)(x)dx = \int_{-\infty}^{+\infty} \overline{(P\varphi)(x)}\psi(x)dx + \frac{\hbar}{i} [ (\overline{\varphi}\psi)(x)]_{-\infty}^{+\infty}[/tex]
Since ##\varphi## and ##\psi## are square integrable, one usually concludes that these functions vanish for ##x\rightarrow \pm\infty##. Thus, the last term in the previous equation vanishes, which implies that the operator P is Hermitian.
However, the textbooks of mathematics tell us that square integrable functions do, in general, not admit a limit for ##x\rightarrow \pm \infty## and therefore they do not necessarily vanish at infinity. There are even functions which are continuous and square summable on ##\mathbb{R}## without being bounded at infinity: an example of such a function is given by
[tex]f(x) = x^2 e^{-x^8\sin^2x}[/tex]
Can one conclude that the operator P is Hermitian in spite of these facts and if so, why?
Challenge 3
Consider the operators ##P = \frac{\hbar}{i} \frac{d}{dx}## and "##Q = ## multiplication by ##x##" acting acting on wave functions depending on ##x ∈ \mathbb{R}##. Since ##P## and ##Q## are Hermitian operators, the operator
[tex]A = PQ^3 + Q^3P[/tex]
also has this property, because its adjoint is given by
[tex]A^\dagger = (PQ^3 + Q^3P)^\dagger = Q^3P + PQ^3 = A[/tex]
It follows that all eigenvalues of ##A## are real. Nevertheless, one easily verifies that
[tex]Af = \frac{\hbar}{i}f[/tex]
with
[tex]f(x) = \left\{\begin{array}{ll}
\frac{1}{\sqrt{2}} |x|^{-3/2}\text{exp}\left(-\frac{1}{4x^2}\right) & \text{for}~x\neq 0\\
0 & \text{for}~x=0
\end{array}\right.[/tex]
which means that ##A## admits the complex eigenvalue ##\hbar/i##. Note that the function ##f## is infinitely differentiable on ##\mathbb{R}## and that it is square integrable, since
[tex]\int_{-\infty}^{+\infty} |f(x)|^2dx = 2\int_0^{+\infty}|f(x)|^2dx = \int_0^{+\infty} x^{-3} \text{exp}\left(-\frac{1}{2x^2}\right)dx= [\text{exp}(-1/(2x^2))]_0^{+\infty} = 1[/tex]
Where is the error?
Challenge 4
Let us consider a particle confined to the interval ##[0, 1]## and described by a wave function ##\psi## satisfying the boundary conditions ##\psi(0) = 0 = \psi(1)##. Then the momentum operator
[tex]P = \frac{\hbar}{i}\frac{d}{dx}[/tex]
is Hermitian, since the surface term appearing upon integration by parts vanishes:
[tex]\int_0^1 \left(\overline{\varphi}(P\psi) - \overline{(P\varphi)}\psi\right)(x)dx = \frac{\hbar}{i}[(\overline{\varphi}\psi)(x)]_0^1 = 0[/tex]
Since P is Hermitian, its eigenvalues are real. In order to determine the latter, we note that the eigenvalue equation,
[tex](P\psi_p)(x) = p\psi_p(x)[/tex]
is solved by ##\psi_p(x) = c_p \text{exp}\left(\frac{i}{\hbar}px\right)## with ##p\in \mathbb{R}## and ##c_\in \mathbb{C}\setminus\{0\}##. The boundary condition ##\psi_p(0) = 0## now implies ##\psi_p = 0##, therefore ##P## does not admit any eigenvalues. Nevertheless, the spectrum of ##P## is the entire complex plane and ##P## does not represent an observable. How can one understand these results which seem astonishing?
Challenge 5
If one introduces polar coordinates in the plane or spherical coordinates in space, then the polar angle ##\varphi## and the component ##L_z## of angular momentum are canonically conjugate variables in classical mechanics. In quantum theory, the variable ##\varphi## becomes the operator of "multiplication of the wave function ##\psi(\varphi)## by ##\varphi## " and ##L_z = \frac{\hbar}{i} \frac{\partial}{\partial \varphi}##, which implies the commutation relation
[tex][L_z,\varphi] = \frac{\hbar}{i}\boldsymbol{1}[/tex]
These operators acting on periodic wave functions (i.e. ##\psi(0) = \psi(2\pi)##) are Hermitian. Furthermore, ##L_z## admits a complete system of orthonormal eigenfunctions ##\psi_m## for ##m\in \mathbb{Z}## and
[tex]L_z \psi_m = m\hbar\psi_m~\text{with}~\psi_m(\varphi) = \frac{1}{\sqrt{2\pi}}\text{exp}(im\varphi).[/tex]
By evaluating the average value of the operator ##[L_z,\varphi]## in the state ##\psi_m## and by taking
into account the fact that ##L_z## is Hermitian, one finds that
[tex]\begin{align*}
\frac{\hbar}{i}
& = \left\langle \psi_m, \frac{\hbar}{i}\boldsymbol{1} \psi_m\right\rangle\\
& = \left\langle \psi_m, L_z\varphi \psi_m\right\rangle - \left\langle \psi_m, \varphi L_z\psi_m\right\rangle\\
& = \left\langle L_z^\dagger\psi_m, \varphi \psi_m\right\rangle - m\hbar\left\langle \psi_m, \varphi \psi_m\right\rangle\\
& = (m\hbar - m\hbar)\left\langle \psi_m, \varphi \psi_m\right\rangle\\
& = 0
\end{align*}[/tex]
Where is the problem?
Challenge 6
Let us add a bit to the confusion of the previous example! In 1927, Pauli noted that the
canonical commutation relation implies Heisenberg’s uncertainty relation ##\Delta P \Delta Q\geq \frac{\hbar}{2}## by virtue of the Cauchy-Schwarz inequality. One can derive, in the same way, the uncertainty relation
[tex] \Delta L_z \Delta \varphi\geq \frac{\hbar}{2}[/tex]
The following physical reasoning shows that this inequality cannot be correct. One can always find a state for which ##\Delta L_z < \frac{\hbar}{4\pi}## and then the uncertainty for the angle ##\varphi## has to be larger than ##2\pi##, which does not have any physical sense, since ##\varphi## takes values in the interval ##[0, 2\pi)##. How is this possible?By the way, this example shows that the uncertainty relation ##\Delta A \Delta B\geq \frac{1}{2}|\left\langle [A,B]\right\rangle|## for any two observables ##A## and ##B## (whose derivation can be found in most quantum mechanics texts) is not valid in such a generality.
Challenge 7
Let us consider a particle of mass ##m## in the infinite potential well (for ##a>0##)
[tex]V(x) = \left\{\begin{array}{ll}
0 & \text{if}~|x|\leq a\\
\infty & \text{otherwise}
\end{array}\right.[/tex]
The Hamiltonian for the particle confined to the inside of the well is simply
[tex]H = - \frac{\hbar^2}{2m} \frac{d^2}{dx^2}[/tex]
Let
[tex]\psi(x) = \left\{\begin{array}{ll}
\frac{\sqrt{15}}{4a^{5/2}}(a^2 - x^2) & \text{if}~|x|\leq a\\
0 & \text{otherwise}
\end{array}\right.[/tex]
be the normalized wave function of the particle at a given time. Since
[tex]H^2\psi = \frac{\hbar^4}{4m^2}\frac{d^4}{dx^4}\psi = 0,[/tex]
the average value of the operator ##H^2## in the state ##ψ## vanishes:
[tex]\left\langle H^2\right\rangle_\psi = \left\langle\psi,H^2\psi\right\rangle = \int_{-a}^a\overline{\psi(x)}(H^2\psi)(x)dx = 0[/tex]
This average value can also be determined from the eigenvalues and eigenfunctions of H,
[tex]H\varphi_n = E_n \varphi_n[/tex]
with
[tex]E_n = \frac{\pi^2\hbar^2}{8ma^2} n^2~\text{for}~n=1,2,3,...[/tex]
by applying the formula
[tex]\left\langle H^2\right\rangle_\psi = \sum_{n=1}^{+\infty} E_n^2 p_n[/tex]
with ##p_n = |\left\langle\varphi_n,\psi\right\rangle|^2##.
Proceeding in this way, one definitely does not find a vanishing result, because ##E_n^2>0## and ##0\leq p_n\leq 1##, ##\sum_{n=1}^{\infty} p_n = 1##. In fact, the calculation yields ##\left\langle H^2\right\rangle_\psi = \frac{15\hbar^4}{8m^2a^4}##. Which one of these two results is correct and where does the inconsistency come from?
References
[1] Mathematical surprises and Dirac's formalism in quantum mechanics by François Gieres.
https://arxiv.org/pdf/quant-ph/9907069
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