Quantum Mechanics homework question on wavefunctions

  • #1
jqmhelios
12
7
Homework Statement
A particle moves in one dimension subject to a potential that is zero in the region
−a ≤ x ≤ a and infinite elsewhere. At a certain time its wavefunction is
ψ = (5a)^(−1/2) cos(πx/2a)+ 2(5a)^(−1/2)sin(πx/a)
.
What are the possible results of the measurement of the energy of this system and
what are their corresponding relative probabilities? What are the possible forms of
the wavefunction immediately after such a measurement? If the energy is immediately
remeasurred, what will now be relative probabilities of the possible outcomes?
Relevant Equations
I assume the solution will involve (H^)f= Ef, the eigenvalue equation for the Hamiltonian operator. Probability should be square of the modulus of the values of an
Absolutely no clue on how to even begin this question due to the exceptionally poor quality of our lectures, who has also flatly refused to give out any solutions, which I could have used to understand what is going on.
I assume the energy has to be obtained by using the eigenfunction equation for a Hamiltonian operator.
The probability should be modulus of the square of a constants, but I do not have the faintest idea on how to obtain that as well.
 
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  • #2
You should get energy eigenfunction of this infinite square well first. Then expand the wave function by these eigenfunction bases. Square of absolute value of expansion coefficient gives probability of finding that energy eigenstate in energy observation.
ref. https://en.wikipedia.org/wiki/Particle_in_a_box
In a glance,
The first term : ground state
The second term : first excited state
 
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Likes Ishika_96_sparkles
  • #3
jqmhelios said:
Homework Statement: A particle moves in one dimension subject to a potential that is zero in the region
−a ≤ x ≤ a and infinite elsewhere. At a certain time its wavefunction is
ψ = (5a)^(−1/2) cos(πx/2a)+ 2(5a)^(−1/2)sin(πx/a)
.
What are the possible results of the measurement of the energy of this system and
what are their corresponding relative probabilities? What are the possible forms of
the wavefunction immediately after such a measurement? If the energy is immediately
remeasurred, what will now be relative probabilities of the possible outcomes?
Relevant Equations: I assume the solution will involve (H^)f= Ef, the eigenvalue equation for the Hamiltonian operator. Probability should be square of the modulus of the values of an

Absolutely no clue on how to even begin this question due to the exceptionally poor quality of our lectures, who has also flatly refused to give out any solutions, which I could have used to understand what is going on.
I assume the energy has to be obtained by using the eigenfunction equation for a Hamiltonian operator.
The probability should be modulus of the square of a constants, but I do not have the faintest idea on how to obtain that as well.
You should get a textbook, such as Griffiths, which is good for wave mechanics.

Note that the guidelines on getting homework help preclude you simply saying you haven't a clue. See the Help pages.
 
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  • #4
Alternatively, there are comprehensive course notes for Infinite Square Well online. E.g. the MIT OpenCourseWare.
 
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  • #5
Statement: Particle in a box problem
Qm_ans_potwell_1d.jpg


Here is the usual outline to proceed towards the solution.

Step 1: Measurement of the energy eigenvalues of this system
The potential ##V(x)## is 0 between ##x=-a## and ##x=a##. Elsewhere it is infinite. See the picture above.
Write the time-independent Schroedinger's equation for this case, within the given limits ##-a \leq x \leq a##
$$\frac{\partial^2\psi}{\partial x^2} + \big( \frac{2m}{\hbar}\big) E \psi =0$$
rewrite this equation using ##\big( \frac{2mE}{\hbar}\big)=k^2## such that we get the familiar linear second order homogeneous differential equation
$$\frac{d^2\psi}{d x^2} + k^2 \psi =0$$
Step 2: Write the general solution for this equation i.e., ##\psi= A \times \sin( \cdots ) \pm \cos( \cdots ) ## and use the boundary conditions ##-a \leq x \leq a## where the wavefunction vanishes to calculate the value of ##k## plus some phase ##\phi## within the bracket of the sine term i.e., ##\sin( \cdots )##.

Step 3: use ##\big( \frac{2mE}{\hbar}\big)=k^2## to calculate E by putting the value of ##k## on the R.H.S. You have now the energy eigenvalue spectrum.

Step 4: Now construct the eigenfuntions and solve for the unknown constant A by using the normalization condition ##\int^a_{-a} \psi^*\psi dx=1##.

Step 5: Post your work here as a pic of the worksheet. Then ask for further guidance.
 

FAQ: Quantum Mechanics homework question on wavefunctions

What is a wavefunction in quantum mechanics?

A wavefunction is a mathematical description of the quantum state of a system. It contains all the information about a particle's position, momentum, and other physical properties. The wavefunction is typically denoted by the Greek letter Psi (ψ) and is a complex-valued function of space and time.

How do you normalize a wavefunction?

To normalize a wavefunction, you need to ensure that the total probability of finding the particle within the entire space is equal to one. This is done by integrating the absolute square of the wavefunction over all space and setting the result equal to one. Mathematically, this is expressed as ∫|ψ(x)|² dx = 1.

What is the physical significance of the absolute square of the wavefunction?

The absolute square of the wavefunction, |ψ(x)|², represents the probability density of finding a particle at a particular position x. This means that if you want to find the probability of the particle being in a specific region, you integrate |ψ(x)|² over that region.

What is the Schrödinger equation and how does it relate to wavefunctions?

The Schrödinger equation is a fundamental equation in quantum mechanics that describes how the wavefunction of a physical system evolves over time. There are two forms: the time-dependent Schrödinger equation and the time-independent Schrödinger equation. Solving the Schrödinger equation gives you the wavefunction, which can then be used to determine the probabilities of various physical properties.

How do boundary conditions affect the solutions to the Schrödinger equation?

Boundary conditions are constraints that the wavefunction must satisfy at the edges of the region where the particle is confined. These conditions are crucial for determining the allowed solutions to the Schrödinger equation. For example, in an infinite potential well, the wavefunction must be zero at the boundaries of the well. These conditions lead to quantization of energy levels and other physical properties.

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