Quantum - Postulate of getting specific momentum p = |A_p|^2

  • #1
laser
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Homework Statement
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Relevant Equations
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WhatsApp Image 2024-05-30 at 15.12.28.jpeg


The first equation states that every wavefunction can be written as a sum of wavefunctions of definite momentum, with A_p being defined as the coefficients in the expansion such that when you take the |wavefunction|^2 it equals 1 - fine.

We then multiply by the wavefunction conjugate and integrate, and using some Kronecker delta trickery we get an expression for A_p. - I'm also okay with this.

But then we say that P(p) = |A_p|^2 is a postulate... From my experience in maths/physics, postulates should be "facts". But here we see that A_p came from somewhere... why are the coefficients in the expansion related to the probability of finding a certain momentum? Is this just experimentally observed and we take it to be true?

Please let me know how you think about this, as I feel like I am thinking of the notion of a "postulate" wrongly.
 
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  • #2
laser said:
But here we see that A_p came from somewhere... why are the coefficients in the expansion related to the probability of finding a certain momentum?
You have
$$\psi(x)=\sum_l A_l ~\psi_l(x)$$ It follows that $$\psi^*(x)=\sum_m A_m^* ~\psi_m^*(x)$$Now suppose you consider $$\int_0^L \psi(x)\psi^*(x)dx~,$$ substitute from above and use some more Kronecker delta trickery. What do you get?
 
  • #3
Firstly, I am not sure why you changed the subscripts when going to the wavefunction conjugate.

Also, the equation you asked me to consider is the same one in my image! So I will get A_m. But I don't see how that answers my question.
 
  • #4
laser said:
Firstly, I am not sure why you changed the subscripts when going to the wavefunction conjugate.
Because they are two different summations and anyway the indices are dummy.
laser said:
Also, the equation you asked me to consider is the same one in my image! So I will get A_m. But I don't see how that answers my question.
It is not the same. Take a second careful look. Like I said, what happens when you substitute the summations with two different indices in the equation that I asked you to consider.
 
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  • #5
kuruman said:
Because they are two different summations and anyway the indices are dummy.

It is not the same. Take a second careful look. Like I said, what happens when you substitute the summations with two different indices in the equation that I asked you to consider.
Ah okay I see. You get the sum over m of |A_m|^2
Screenshot_2.png

which is equal to the above image.

As it turns out, the above image is also equal to the probability density over all the space = 1! (from another postulate)

This leads to another question: why is |A_p|^2 = probability density a postulate as well as the |wavefunction|^2 = probability density? Surely just one of them being a postulate is enough!
 
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  • #6
laser said:
This leads to another question: why is |A_p|^2 = probability density a postulate as well as the |wavefunction|^2 = probability density? Surely just one of them being a postulate is enough!
The postulate is
$$\int_0^L \psi(x)\psi^*(x)dx=1.\tag{1}$$
Please provide the exact statement of the problem as was given to you and how "postulate" is mentioned in it. Note that $$\sum_p |A_p|^2=1$$ is another way of saying the same thing as equation (1).
 
  • #7
kuruman said:
The postulate is
$$\int_0^L \psi(x)\psi^*(x)dx=1.\tag{1}$$
Please provide the exact statement of the problem as was given to you and how "postulate" is mentioned in it. Note that $$\sum_p |A_p|^2=1$$ is another way of saying the same thing as equation (1).
I'm just reading some notes, it says that equation (1) is a postulate, but it also said that the sum of |A_p|^2 = 1 is also a postulate. Probably just a mistake in the notes, as either postulate can be used to derive the other!

Source: https://oyc.yale.edu/sites/default/files/notes_quantum_9.pdf page 21 equation (34)
 
  • #8
I wouldn't worry about it.
 
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