Quick QM: Why Does Schrodinger Eq Being 1st Order Matter?

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In summary, the Schrödinger equation is first order in time and this has implications for the probability interpretation. When solving by separation of variables, the time dependent part of the solution is \exp{iEt/\hbar}, while the position dependent part satisfies the time-independent SE. According to the Born interpretation, the product of the solution and its complex conjugate represents a probability density function for the particle's position. If the time dependence of the SE was not first order, it would result in negative probabilities. However, it is still unclear how this would occur since the norm squared of the solution would still be positive.
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Thrice
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The schrodinger eq is 1st order in t. Why does that matter to the probability interpretation?

Should be an easy question, but I can't seem to get it.
 
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  • #2
Here's a suggestion you might want to investigate. When solving the SE by the method of separation of variables, we find that the time dependant part of the solution is [itex]\exp{iEt/\hbar}[/itex], and the position dependant part satisfies the time-independant SE. Denote [itex]\psi(x)[/itex] the solution to the time independant SE for a given potential. Then the general solution to the SE is [itex]\Psi(x,t)=\psi(x)e^{iEt/\hbar}[/itex], and according to the Born interpretation, [itex]\Psi \Psi^*[/itex] is a probability density function for the position of the particle. But [itex]\Psi \Psi^* = \psi\psi^*[/itex]. I.e. the probability density is is time independant!

So the question is, would the time dependant part of the [itex]\Psi[/itex] still be such that the probability is time independant if the t "dependance" of the SE was not of first order?
 
  • #3
Interestingly, Schrödinger originally started with a relativistic equation, but didn't know what to do with the negative probability densities that resulted, so came up with the final non-relativistic equation instead.
 
  • #4
quasar987 said:
Here's a suggestion you might want to investigate. When solving the SE by the method of separation of variables, we find that the time dependant part of the solution is [itex]\exp{iEt/\hbar}[/itex], and the position dependant part satisfies the time-independant SE. Denote [itex]\psi(x)[/itex] the solution to the time independant SE for a given potential. Then the general solution to the SE is [itex]\Psi(x,t)=\psi(x)e^{iEt/\hbar}[/itex], and according to the Born interpretation, [itex]\Psi \Psi^*[/itex] is a probability density function for the position of the particle. But [itex]\Psi \Psi^* = \psi\psi^*[/itex]. I.e. the probability density is is time independant!

So the question is, would the time dependant part of the [itex]\Psi[/itex] still be such that the probability is time independant if the t "dependance" of the SE was not of first order?
Ok I understand what you said there (I think), but I can't make the jump to what would happen if it wasn't 1st order in t. I know how to derive the equation from dealing with wave packets, I know why it's 1st order & how to get the time independent SE eigenvalue equation.

Call it a lack of imagination. I can't see how it could be different. I know the difference between the SE & the familiar wave equation, but I can't see how to get probabilities out of the latter.
 
  • #5
It should have to do with what Daverz said. I.e. that a different order in t will give us negative probabilities... but how could that be? Whatever the solution [itex]\Psi(x,t)[/itex] to a modified SE, the complex conjugate of [itex]\Psi[/itex] is still it's norm squared, which is still positive no matter what. :confused:
 
  • #6
Bump. I was going through old posts & needed some closure here. Thanks to whoever moved this.
 

FAQ: Quick QM: Why Does Schrodinger Eq Being 1st Order Matter?

What is the Schrodinger equation and why is it important in quantum mechanics?

The Schrodinger equation is a fundamental equation in quantum mechanics that describes the behavior of quantum systems. It is important because it allows us to calculate the probability of finding a particle in a particular state, which is crucial for understanding the behavior of quantum systems.

Why is the Schrodinger equation considered a first-order equation?

The Schrodinger equation is considered a first-order equation because it only involves first derivatives of the wave function with respect to time. This is in contrast to second-order equations, which involve second derivatives of the wave function.

What is the significance of the first-order nature of the Schrodinger equation?

The first-order nature of the Schrodinger equation is significant because it allows us to predict the future behavior of a quantum system based on its current state. This is important because it gives us a way to model and understand the behavior of quantum systems, which can be very complex and unpredictable.

How is the first-order nature of the Schrodinger equation related to the uncertainty principle?

The first-order nature of the Schrodinger equation is related to the uncertainty principle because it is through the first-order derivative that we can calculate the probability of finding a particle in a particular state. The uncertainty principle states that we cannot know both the position and momentum of a particle with absolute certainty, and the first-order nature of the Schrodinger equation is a direct result of this fundamental principle of quantum mechanics.

Can the Schrodinger equation be used to solve all quantum mechanical problems?

No, the Schrodinger equation cannot be used to solve all quantum mechanical problems. While it is a fundamental equation in quantum mechanics, it is only applicable to non-relativistic systems and cannot be used to describe particles moving at speeds close to the speed of light. Additionally, it does not account for certain phenomena such as particle interactions and quantum tunneling, which require more complex equations.

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