Radial distribution of a 3d orbital

In summary, to sketch the radial distribution of a $3d_{x^2-y^2}$ orbital, one can refer to resources such as Atomic orbitals on wiki or The Orbitron. This orbital has $0$ radial nodes and two angular nodes.
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Dethrone
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How do I sketch the radial distribution of a $3d_{x^2-y^2}$ orbital? :D
 
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  • #2
Rido12 said:
How do I sketch the radial distribution of a $3d_{x^2-y^2}$ orbital? :D

Hey Rido!

Check out for instance Atomic orbitals on wiki?
It has some nice and different types of representations for the $3d_{x^2-y^2}$ orbital. (Mmm)
 
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Thanks ILS and jacobi! (Cool)

I was able to find this image, which I'm pretty sure is the radial distribution of the 3D orbital.

View attachment 3854

In general, an orbital has $n-l-1$ radial nodes, and in this case, $n=3$, $l=2$, so there are $0$ radial nodes. This agrees with the image because there are no roots on the graph. There are however, two angular nodes / nodal planes that are perpendicular to the axis, but does not need to be reflected in the graph.
 

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To sketch the radial distribution of a $3d_{x^2-y^2}$ orbital, you will need to follow these steps:

1. Start by drawing a Cartesian coordinate system with the origin at the center. This will represent the nucleus of the atom.

2. Next, draw three perpendicular axes (x, y, and z) that intersect at the origin. These axes will help you visualize the orientation of the orbital.

3. The $3d_{x^2-y^2}$ orbital is a complex orbital with two nodal planes, one along the x-axis and one along the y-axis. These nodal planes divide the orbital into four lobes, with two lobes along the x-axis and two lobes along the y-axis.

4. To sketch the radial distribution, start by drawing the four lobes as four elongated ovals, two along the x-axis and two along the y-axis. These lobes represent the regions where the electron density is highest.

5. Next, draw the nodal plane along the x-axis as a flat line passing through the center of the x-axis. This plane represents the region where the electron density is zero.

6. Similarly, draw the nodal plane along the y-axis as a flat line passing through the center of the y-axis.

7. The electron density in the lobes decreases as you move away from the nucleus, so make sure to draw the lobes with decreasing size as you move away from the origin.

8. Finally, add shading or color to the lobes to represent the different phases of the orbital. The lobes along the x-axis will have a different phase than the lobes along the y-axis.

This sketch will give you a visual representation of the radial distribution of a $3d_{x^2-y^2}$ orbital. Remember, the shape and orientation of an orbital can vary depending on the atom and its electronic configuration, so this sketch is just a general representation.
 

FAQ: Radial distribution of a 3d orbital

What is the radial distribution of a 3d orbital?

The radial distribution of a 3d orbital refers to the probability of finding an electron at a given distance from the nucleus in a 3d orbital. It shows the likelihood of finding an electron at different distances from the nucleus.

How is the radial distribution of a 3d orbital different from other orbitals?

The radial distribution of a 3d orbital is different from other orbitals because it has a more complex shape. It has two angular nodes, which are regions where the probability of finding an electron is zero. This makes the 3d orbital more diffuse and spread out compared to other orbitals.

What factors affect the radial distribution of a 3d orbital?

The radial distribution of a 3d orbital is affected by the principal quantum number, which determines the energy level of the orbital, and the angular momentum quantum number, which determines the shape of the orbital. The number of electrons in the orbital also affects the radial distribution, as the presence of other electrons creates repulsion and can alter the shape of the orbital.

How does the radial distribution of a 3d orbital impact chemical bonding?

The radial distribution of a 3d orbital can impact chemical bonding as it determines the location and probability of finding electrons around the nucleus. This affects the strength and type of chemical bonds that can be formed between atoms. For example, the more diffuse nature of the 3d orbital allows for greater overlap with other orbitals, leading to stronger bonds.

Can the radial distribution of a 3d orbital change?

Yes, the radial distribution of a 3d orbital can change depending on external factors such as the presence of other electrons, electric fields, or changes in the energy level. These changes can alter the shape and probability of finding electrons in the orbital, which can impact the chemical properties and behavior of the atom.

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