Reaction Products of Ethylene with Fluorine Gas

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In summary, the products when ethylene reacts with fluorine gas can potentially be 2 hydrogen molecules and 2 carbon tetrafluoride, or 1 carbon, 2 hydrogen fluoride, and 1 carbon tetrafluoride. Both reactions are theoretically possible due to the high reactivity of fluorine, but the second reaction may be unlikely as it involves breaking a double bond. Further input from a chemist is welcome.
  • #1
tandoorichicken
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just a basic rookie question. What are the products when ethylene reacts with fluorine gas (i.e., burned in presence of fluorine)?

I was given the following data:
[itex]H_2 + F_2 \rightarrow 2HF \Delta H^{o} = -537 kJ [/itex]
[itex]C + 2F_2 \rightarrow CF_4 \Delta H^{o} = -680 kJ [/itex]
[itex]2C + 2H_2 \rightarrow C_2 H_4 \Delta H^{o} = +52.3 kJ [/itex]

I used the starting formula [itex] C_2 H_4 + 4F_2 [/itex]

I balanced out equations and got two possibilities, and I'm not sure which one to go with. In one, it forms 2 hydrogen molecules and 2 carbon tetrafluoride, and in the other it forms 1 C, 2 HF and 1 carbon tetrafluoride. BOTH of these balance out and I don't know which one to go with.
 
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Since the Fluorine is the most reactive element among the electronegative/nonmetal ones,i'd say that both reactions are in theory possible,since the fluorine has the power to knock both C and H from such compounds.However,i think that it may add(itonate ..??,is this the word) to the C_{2}H_{4} breaking the double bond and resulting something like
C_{2}F_{2}H_{2}.However,i find the second reaction (almost) impossble.

Daniel.

P.S.Any chemist is invited to express his/her opinion. :smile:
 
  • #3


The reaction between ethylene (C2H4) and fluorine gas (F2) can result in two possible products depending on the reaction conditions. The first possibility is the formation of 2 hydrogen molecules (H2) and 2 carbon tetrafluoride (CF4) molecules. This reaction is balanced by the equation C2H4 + 4F2 → 2H2 + 2CF4. The second possibility is the formation of 1 carbon (C) atom, 2 hydrogen fluoride (HF) molecules, and 1 carbon tetrafluoride (CF4) molecule. This reaction is balanced by the equation C2H4 + 4F2 → C + 2HF + CF4. Both reactions are exothermic, meaning they release heat energy.

The choice between the two reactions depends on the reaction conditions, such as temperature and pressure. At high temperatures and low pressures, the first reaction is favored and will likely produce more products. On the other hand, at low temperatures and high pressures, the second reaction is favored and will likely produce more products.

It is important to note that both reactions are possible and can occur simultaneously, resulting in a mixture of the two products. The exact ratio of the products will depend on the reaction conditions. Additionally, there may also be other minor products formed, such as carbon monofluoride (CF) and carbon difluoride (CF2).

In summary, the reaction between ethylene and fluorine gas can result in the formation of 2H2 + 2CF4 or C + 2HF + CF4 depending on the reaction conditions. Both reactions are exothermic and can occur simultaneously, producing a mixture of products.
 

FAQ: Reaction Products of Ethylene with Fluorine Gas

What are the reaction products of ethylene and fluorine gas?

The reaction between ethylene and fluorine gas produces a variety of products, including difluoroethane, 1,1-difluoroethene, 1,2-difluoroethene, and 1,1,2-trifluoroethane. The specific products formed depend on the reaction conditions and catalyst used.

What is the mechanism of the reaction between ethylene and fluorine gas?

The reaction between ethylene and fluorine gas is a radical addition reaction. It begins with the formation of ethylene radicals from the breaking of the double bond in ethylene. These radicals then react with fluorine gas to form a variety of products through different radical pathways.

What are the industrial applications of the reaction between ethylene and fluorine gas?

The reaction between ethylene and fluorine gas is commonly used in the production of fluorinated compounds, such as refrigerants, solvents, and plastics. These compounds have a wide range of industrial applications, including use in refrigeration, air conditioning, and as chemical intermediates.

How does the reaction between ethylene and fluorine gas contribute to environmental concerns?

The reaction between ethylene and fluorine gas can produce harmful byproducts, such as hydrogen fluoride and fluorocarbons, which contribute to environmental concerns. These byproducts can contribute to air pollution and damage the ozone layer.

Is the reaction between ethylene and fluorine gas safe for human health?

The reaction between ethylene and fluorine gas can be hazardous to human health if proper safety precautions are not taken. Both ethylene and fluorine gas are highly reactive and can cause severe burns or respiratory problems if inhaled. It is important to handle these chemicals with caution and in a well-ventilated area.

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