Redox Titration: How to Determine Fe (aq)2+ Concentration

In summary, redox titration is a method used to determine the concentration of Fe(aq)2+ in a solution by measuring the amount of a known oxidizing agent needed to completely react with the iron ions. This involves using a burette to slowly add the oxidizing agent, typically potassium permanganate, to the iron solution until a color change occurs, indicating the completion of the reaction. By knowing the volume and concentration of the oxidizing agent, the concentration of Fe(aq)2+ can be calculated using the balanced chemical equation. Redox titration is a common technique used in analytical chemistry for accurate and precise determination of iron concentration in various samples.
  • #1
hihowareu
4
2
To determine the concentration of Fe (aq)2+ by a redox titration, we could use an acidified
standard solution of

A. Sn2+
B. Pb2+
C. HCl
D. H2O2

I know the answers H2O2, but i don't know how to get it. How doe redox titrations work?
 
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  • #2
Redox titration works as every other kind of titration. You need to select reaction with well known stoichiometry and react substance that you want to determine with substance of know concentration, somehow detecting the moment when amount of the substance added was stoichiometric.

http://www.titrations.info/

http://www.titrations.info/potentiometric-titration

In this particular case you need to select substance that is able to react with Fe2+, oxidizing it to Fe3+. Not much choice.

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FAQ: Redox Titration: How to Determine Fe (aq)2+ Concentration

1. What is redox titration?

Redox titration is a laboratory technique used to determine the concentration of an unknown substance by measuring the volume of a known reactant required to completely react with the unknown substance. This method is based on the principles of oxidation and reduction reactions, where one substance is oxidized while the other is reduced.

2. Why is redox titration used to determine Fe (aq)2+ concentration?

Iron (II) ions, represented as Fe (aq)2+, can easily undergo oxidation and reduction reactions. This makes it a suitable substance to use for redox titration as it can easily react with a known substance, allowing for accurate determination of its concentration.

3. How is the concentration of Fe (aq)2+ determined using redox titration?

In redox titration, a known volume of a standard solution, such as potassium permanganate, is added to a measured volume of the sample containing Fe (aq)2+. The reaction between the two substances is monitored until the endpoint is reached, which is indicated by a color change. The volume of the standard solution used can then be used to calculate the concentration of Fe (aq)2+ in the sample.

4. What are the factors that can affect the accuracy of redox titration results?

Some factors that can affect the accuracy of redox titration results include the purity and concentration of the standard solution, the accuracy of the equipment used, and any environmental factors that may affect the reaction, such as temperature or air exposure. It is important to carefully control and monitor these factors to obtain accurate results.

5. What are some possible sources of error in redox titration?

Possible sources of error in redox titration may include incorrect measurement of volumes, contamination of solutions, incomplete reactions, or human error in reading the endpoint. It is important to carefully follow proper laboratory techniques and procedures to minimize these sources of error and obtain accurate results.

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