Reference Electrostatic Potential

In summary, the criteria for choosing infinity as zero potential is based on the mathematical form of the Coulombic potential and the physical meaning of the electromagnetic force having an infinite range. This choice allows for the potential of an object to be determined by the work necessary to bring it from infinity to its position. However, when dealing with infinities, complications can arise and it may be necessary to choose a different reference point for the potential.
  • #1
HAMJOOP
32
0
What is the criteria in choosing infinity as zero potential ?

e.g. an infinite plate with uniform charge density.

What is the physical meaning of not be able to choose a position as reference potential ??
 
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  • #2
My understanding of it is that, mathematically, because the functional form of the Coulombic potential is $$V = \frac{kq}{r}$$ no real number results in a value of zero for the potential. The only "value" of r that satisfies this is infinity. Physically, as I understand it, it means that the electromagnetic force has an infinite range, because the electric potential has a value all the way out to infinity.
 
  • #3
You can chose whatever you like for zero potential, the only way to connect electrostatic potential to something physical is to take its gradient, so it is underconstrained up to a constant term.

V or V + 301.20 will both lead to the same electric field, E = -grad(V) == -grad(V + 301.20). So whether you define the potential to be zero or 301.20 at infinity doesn't matter. Likewise, you can put the zero potential wherever you want. Put it in Norway for all the physics cares, you'll get the same electric field as a result.

You might just spend more time doing unnecessary mathematics.
 
  • #4
If I have an infinitely large conductor plate with uniform charge density.

E = σ/2ε (suppose it is in x direction)

V = -∫E dx (from x0 to x)

V = -(σ/2ε)(x - x0 )

From this expression, I can't choose reference at infinity (i.e. x0 --> infinity) because the whole expression V would be infinity.

Is it because there is infinitely many charges ??
 
  • #5
Essentially, any time you actually have CHARGES out at infinity, you won't be able to take infinity as your reference point, just like you can't take the location of a point charge as a reference point. The potential will blow up in either case.
 
  • #6
HAMJOOP said:
If I have an infinitely large conductor plate with uniform charge density.

As mikeph said, you can choose the zero point of potential to be anywhere you want, so we generally choose whatever makes the problem easiest to solve.

For the infinite plate with uniform charge density, it's most convenient to take the surface of the plate as the point of zero potential.
 
  • #7
HAMJOOP said:
What is the criteria in choosing infinity as zero potential ?

e.g. an infinite plate with uniform charge density.

What is the physical meaning of not be able to choose a position as reference potential ??

The reason infinity is chosen as zero potential is to be able to say that "the potential of an object is the work necessary to bring that object from infinity to the position of that potential". This holds for any conservative field like gravity or electrostatics.

You can't always have zero potential at infinity, for example a charged wire of infinite length cannot have zero potential at infinity. Same for your infinite charged plate.
 
  • #8
HAMJOOP said:
From this expression, I can't choose reference at infinity (i.e. x0 --> infinity) because the whole expression V would be infinity.

How?
 
  • #9
HAMJOOP said:
If I have an infinitely large conductor plate with uniform charge density.

E = σ/2ε (suppose it is in x direction)

V = -∫E dx (from x0 to x)

V = -(σ/2ε)(x - x0 )

From this expression, I can't choose reference at infinity (i.e. x0 --> infinity) because the whole expression V would be infinity.

Is it because there is infinitely many charges ??

Yes. When dealing with infinities, life can get complicated! As you found out, you cannot assign zero potential to your plate at infinity.

You can assign it as zero at the plate as another poster has suggested, or you can assign zero potential to any point a finite distance from the plate, but not an infinite distance.

BTW the E field for a conductor is E = σ/ε. It's σ/2ε for a charged dielectric sheet.
 

FAQ: Reference Electrostatic Potential

What is Reference Electrostatic Potential?

Reference Electrostatic Potential (ESP) is a measure of the electrostatic potential energy at a point in space, relative to a reference point. It is used to describe the distribution of electrons in a molecule or system and is important in understanding molecular properties and interactions.

How is Reference Electrostatic Potential calculated?

Reference Electrostatic Potential is calculated using quantum mechanical methods, such as Density Functional Theory (DFT) or Hartree-Fock (HF) theory. These methods use mathematical equations to solve for the electron density distribution around a molecule or system, which can then be used to calculate the ESP at different points in space.

What is the significance of Reference Electrostatic Potential in chemistry?

Reference Electrostatic Potential is an important concept in chemistry as it provides a quantitative measure of the electron density distribution in a molecule or system. It can be used to predict and understand molecular properties such as reactivity, stability, and intermolecular interactions. It is also used in drug design and material science to study the interactions between molecules and their environment.

How is Reference Electrostatic Potential visualized?

Reference Electrostatic Potential can be visualized using color-coded maps, where blue represents regions with low potential and red represents regions with high potential. These maps can be overlaid on molecular structures to provide a visual representation of the distribution of electrons in a molecule. They can also be used to compare the ESP of different molecules and predict their reactivity and interactions.

Can Reference Electrostatic Potential be experimentally measured?

No, Reference Electrostatic Potential cannot be directly measured experimentally. It is a theoretical concept that is calculated using mathematical models. However, its predictions can be verified through experimental techniques such as nuclear magnetic resonance (NMR) spectroscopy or X-ray crystallography, which can provide information about the electron density distribution in a molecule or system.

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