Rydberg constant for hydrogen atom and Balmer series

  • #1
sss1
50
2
Homework Statement
Does the Rydberg constant change for different Balmer series lines? Like H_α, H_β, etc. according to the formula, it shouldn’t right, it should only change with the amount of electrons and nucleons? I googled some data and I put them into the formula 1/lambda=R(1/n_f^2-1/n_i^2) and tried for several wavelengths for hydrogen (n_f=2), I ended up with pretty close values but with minor differences. I was wondering if this is due to the accuracy of the instruments measuring the wavelength? Or is it meant to differ for different Balmer series lines?
Relevant Equations
1/lambda=R(1/n_f^2-1/n_i^2)
^^
 
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  • #2
The Rydberg constant is a combination of fundamental constants and so it does not change. The discrepancies you are seeing are probably due to the fact that the Bohr model is only an approximate model and ignores some effects, such as fine structure. Or it could also be due to the accuracy of the measurements, as you said.
 
  • #3
phyzguy said:
The Rydberg constant is a combination of fundamental constants and so it does not change. The discrepancies you are seeing are probably due to the fact that the Bohr model is only an approximate model and ignores some effects, such as fine structure. Or it could also be due to the accuracy of the measurements, as you said.
Alright, thanks!
 

FAQ: Rydberg constant for hydrogen atom and Balmer series

What is the Rydberg constant for hydrogen?

The Rydberg constant for hydrogen is approximately 1.097 x 10^7 m^-1. It is a fundamental physical constant used in atomic physics to describe the wavelengths of spectral lines of many chemical elements.

How is the Rydberg constant related to the Balmer series?

The Rydberg constant is used in the formula that predicts the wavelengths of the spectral lines in the Balmer series. The Balmer series describes the emission spectrum of hydrogen when an electron transitions from a higher energy level (n ≥ 3) to the n=2 energy level.

What is the formula for the Balmer series using the Rydberg constant?

The formula for the Balmer series is given by 1/λ = R_H (1/2^2 - 1/n^2), where λ is the wavelength of the emitted light, R_H is the Rydberg constant for hydrogen, and n is the principal quantum number of the electron's initial energy level (n > 2).

Why is the Rydberg constant important in spectroscopy?

The Rydberg constant is crucial in spectroscopy because it allows scientists to predict and analyze the spectral lines of hydrogen and other elements. This helps in understanding atomic structure and the energy levels within an atom.

Can the Rydberg constant be used for elements other than hydrogen?

Yes, the Rydberg constant can be used for elements other than hydrogen, but it needs to be adjusted for the reduced mass of the electron and nucleus in those elements. For hydrogen-like atoms (single electron systems), a modified Rydberg constant specific to that element is used.

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