Schrodinger Eq. & Energies: Are Values Always Positive?

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In the context of the Schrödinger equation, energy values are not always positive; they can indeed be negative. This occurs particularly when a particle is in a bound state, where its energy is less than the threshold required to escape. The existence of negative energy values is crucial, as it indicates that there is a lowest energy eigenvalue that prevents the system from losing an infinite amount of energy. Understanding these energy values is essential for analyzing quantum systems effectively. Overall, the discussion emphasizes the significance of negative energy in bound states within quantum mechanics.
oddiseas
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just a question about the energies associted wuth the schrodinger equation> are the energy values always positive values. I thought that since when the eigenfunctions exist the particle is in a bound state, that the energy should be less than that required to escape a bound state and should be negative.
 
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oddiseas said:
just a question about the energies associted wuth the schrodinger equation> are the energy values always positive values. I thought that since when the eigenfunctions exist the particle is in a bound state, that the energy should be less than that required to escape a bound state and should be negative.

Yes, the energies can be negative. However, there must exist a lowest energy eigenvalue, otherwise the system could lose an infinite amount of energy.
 
Time reversal invariant Hamiltonians must satisfy ##[H,\Theta]=0## where ##\Theta## is time reversal operator. However, in some texts (for example see Many-body Quantum Theory in Condensed Matter Physics an introduction, HENRIK BRUUS and KARSTEN FLENSBERG, Corrected version: 14 January 2016, section 7.1.4) the time reversal invariant condition is introduced as ##H=H^*##. How these two conditions are identical?

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