Separating Schrodinger's Equation

In summary, the Time Dependent Schrodinger Equation can be separated into a time-independent Schrodinger equation and a time evolution equation by assuming that energy is conserved and that the potential is time-independent. This results in the equation being split into an equation independent of x and an equation independent of t, with a constant E representing the energy.
  • #1
MiCasilla
I'm looking for the mathematical demonstration that the Time Dependent Schrodinger Equation can be separated into time-independent Schrodinger equation and time evolution equation.

Does anybody know a link which such demonstration?
 
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  • #2
okay:


iħ ∂Ψ/∂t = - ħ2/2m ∂2Ψ/∂x2 + VΨ

Okay now assuming energy is conserved (i.e. a closed sytsem)and thus V is time-independant:

Ψ(x,t) = u(x)T(t)

subsituting that into the TDSE:

iħ 1/T dT/dt = - 1/u ħ2/2m d2u/dx2

The left hand side is noe independent of x and the right is now independant of t, yet this equation must hold true for all values of x and t therfore:

iħ dT/dt = ET

Where E is a constant, thus:

- ħ/2m d2u/dx2 + V(x)u = Eu
 
  • #3
Thank you, very very much!
 

FAQ: Separating Schrodinger's Equation

What is Schrodinger's equation?

Schrodinger's equation is a mathematical equation that describes the behavior of quantum particles, such as electrons, in a given system.

Why is it important to separate Schrodinger's equation?

Separating Schrodinger's equation allows us to solve for the wave function of a quantum system, which gives us information about the probability of finding a particle at a certain location.

How do you separate Schrodinger's equation?

To separate Schrodinger's equation, we use the method of separation of variables, which involves assuming that the wave function can be expressed as a product of two functions, one depending on time and the other depending on position.

What are the two parts of Schrodinger's equation?

Schrodinger's equation has two parts: the time-independent part, which describes the potential energy of the system, and the time-dependent part, which describes the evolution of the wave function over time.

What does solving Schrodinger's equation tell us about a system?

Solving Schrodinger's equation gives us the wave function, which can be used to calculate the probability of finding a particle in a certain location. It also gives us information about the energy levels and possible states of the system.

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