Solid State Physics-simple question on lattice vacancies

The equation provided could potentially be used, but it is unclear if it is applicable in this scenario.
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Homework Statement



If silver melts at 9620C and contains an intrinsic relative concentration of 3*10^(-7) lattice vacancies, estimate the energy required to remove an atom from the interior of the crystal lattice.


Homework Equations



The above is a past exam question and the equation wasn't given but I'm pretty sure, the following, which gives the number of vacancies n in thermal equilibrium is the relevant one.

[itex]
\frac{n}{N}=exp (\frac{-E_v}{k_BT})
[/itex]

The Attempt at a Solution



It probably simply is a matter of plugging into the above equation, with n/N=3*10^(-7),
Ev being what we need.

The T is what I'm a little confused about if it was a temperature other then the melting point, I'd be happy to just plug it in. At the melting point however, there is no crystal and hence the question of vacancies doesn't arise.

Or is it simply that the crystal is at the melting point without actually having melted?
 
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  • #2


I would first clarify the question with the person who posted it. It is important to have all the necessary information and context in order to accurately estimate the energy required to remove an atom from the interior of the crystal lattice. Without knowing the specific temperature at which the crystal is being studied, it is difficult to accurately calculate the energy required.

Assuming that the crystal is at the melting point of silver, it is possible that the crystal is still present but in a liquid form. In this case, the vacancies may still exist and the equation provided could be used to estimate the energy required. However, it is also possible that the crystal has completely melted and in this case, the equation may not be applicable as there would be no crystal lattice or vacancies.

In summary, as a scientist, it is important to clarify the question and gather all necessary information before attempting to provide an answer. Without knowing the specific temperature and conditions of the crystal, it is difficult to accurately estimate the energy required to remove an atom from the interior of the crystal lattice.
 

Related to Solid State Physics-simple question on lattice vacancies

1. What are lattice vacancies in solid state physics?

Lattice vacancies are defects in the crystal lattice of a solid material where an atom or a group of atoms is missing from its expected position. These vacancies can occur due to thermal energy or external forces, and can significantly affect the physical and mechanical properties of a material.

2. How do lattice vacancies affect the properties of a material?

Lattice vacancies can affect the properties of a material in various ways. They can decrease the density and increase the electrical resistivity of a material. They can also affect the mechanical strength and thermal conductivity of a material. In some cases, lattice vacancies can also lead to the formation of new phases and alter the material's magnetic properties.

3. Can lattice vacancies be controlled or prevented?

In most cases, lattice vacancies cannot be completely prevented, as they are a natural occurrence in solid materials. However, they can be controlled to some extent by adjusting the processing conditions and material composition. For example, the addition of certain impurities or the use of specific processing techniques can reduce the number of lattice vacancies in a material.

4. How are lattice vacancies detected in solid materials?

Lattice vacancies can be detected through various techniques such as X-ray diffraction, electron microscopy, and positron annihilation spectroscopy. These techniques allow scientists to study the atomic structure of a material and identify any missing atoms or defects in the lattice.

5. Can lattice vacancies be beneficial in certain applications?

Yes, lattice vacancies can be beneficial in some applications. For example, they can increase the electrical resistivity of a material, making it more suitable for electronic devices. In some cases, lattice vacancies can also enhance the catalytic activity of materials, making them useful for various chemical reactions.

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