Specific heat of solid of one dimensional quartic oscillators

In summary, the conversation discusses a system of N weakly interacting particles at high temperature, each with mass M and performing one-dimensional oscillations with a restoring force proportional to x^3. The goal is to calculate the heat capacity of this system, using classical statistical mechanics. The relevant equations include the spring constant, energy of one oscillator, and partition function. The solution involves finding the partition function by solving the integral of exp(-x^4), which can be done using the gamma function.
  • #1
sabinscabin
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Homework Statement



A system consists of N very weakly interacting particles at temperature T sufficiently high so that classical stat mech is applicable. Each particle has mass M and is free to perform one dimensional oscillations about its equilibrium position. Calculate the heat capacity of this system of particles if the restoring force is proportional to x^3.


Homework Equations



spring constant = q
energy of one oscillator E = p^2 / 2m + qx^4 / 4

partition function: Z = integral ( exp(-BE ) dx dp
both integrals from -inf to +inf

where B = 1/kT

The Attempt at a Solution



Cv = N d/dT (average E)

average E = - d / dB [ ln Z ]
Z = integral [exp (-Bp^2/2m) dp ] * integral [exp (-Bqx^4/4) dx ]

the first integral is simply sqrt(pi * 2m / B )
I have no idea how to find the integral of exp(-x^4), so I can't find this partition function.
 
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  • #2
Try the substitution [itex]t=\frac{\beta q x^4}{4}[/itex] and make use of the gamma function:

[tex]\Gamma(z)\equiv \int_0^\infty t^{z-1}e^{-t}dt[/tex]
 

FAQ: Specific heat of solid of one dimensional quartic oscillators

1. What is the definition of specific heat for solid one-dimensional quartic oscillators?

The specific heat of a solid one-dimensional quartic oscillator refers to the amount of heat required to raise the temperature of the material by one degree Celsius per unit mass, while keeping the volume and pressure constant.

2. How is the specific heat of solid one-dimensional quartic oscillators measured?

The specific heat of solid one-dimensional quartic oscillators can be measured experimentally by using calorimetry techniques. This involves measuring the change in temperature of the material when a known amount of heat is added or removed.

3. What factors affect the specific heat of solid one-dimensional quartic oscillators?

The specific heat of solid one-dimensional quartic oscillators is affected by various factors such as the composition and structure of the material, temperature, and pressure. It can also be influenced by the presence of impurities or defects in the material.

4. Why is the specific heat of solid one-dimensional quartic oscillators important?

The specific heat of solid one-dimensional quartic oscillators is important in understanding the thermal properties of materials. It helps in predicting how a material will respond to changes in temperature and in designing materials for specific applications.

5. How does the specific heat of solid one-dimensional quartic oscillators compare to other types of oscillators?

The specific heat of solid one-dimensional quartic oscillators is higher than that of linear oscillators, which have a constant specific heat regardless of temperature. It is also higher than that of cubic oscillators, which have a specific heat that decreases with increasing temperature.

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