The energy term in Schroedinger equation

In summary, the energy in the time-independent Schroedinger equation H|Ψ>=E|Ψ> is the total energy of the system, which is E=kinetic energy +V where V is the potential energy. When solving problems in quantum mechanics, like scattering problems, the energy is obtained as the expectation value of the Hamiltonian and is not necessarily equal to the potential energy of the system. This is because the potential energy operator is different from the Hamiltonian and the eigenstates of the Hamiltonian do not necessarily correspond to those of the potential energy. In quantum mechanics, it is possible for the total energy to be less than the potential energy, which is classically forbidden. This is due to the nature of the Schrod
  • #36
DrClaude said:
The OP clearly mentioned a potential step, and in my post I discussed a potential barrier, which would give the same conceptual problem.Yes, that was the basic confusion. I and others have couched it in QM terms, discussing the difference between operators and expectation values. By the way, "the sum of the 2" doesn't make sense in this context.

Yes, you're right. I seem to have fallen into the same trap, conflating the two meanings of 'energy' in this context.
 
<h2> What is the energy term in the Schroedinger equation?</h2><p>The energy term in the Schroedinger equation is a mathematical representation of the total energy of a quantum mechanical system, including both its kinetic and potential energy components.</p><h2> How is the energy term calculated in the Schroedinger equation?</h2><p>The energy term is calculated by solving the Schroedinger equation, which is a differential equation that describes the behavior of quantum systems. The energy is one of the solutions to the equation, along with the wave function.</p><h2> Why is the energy term important in the Schroedinger equation?</h2><p>The energy term is important because it allows us to understand and predict the behavior of quantum systems. It helps us determine the allowed energy levels and the corresponding wave functions of a system.</p><h2> How does the energy term affect the behavior of particles in a quantum system?</h2><p>The energy term affects the behavior of particles in a quantum system by determining the probability of finding the particle in a particular energy state. The higher the energy, the lower the probability of finding the particle in that state.</p><h2> Can the energy term be negative in the Schroedinger equation?</h2><p>Yes, the energy term can be negative in the Schroedinger equation. This indicates that the system has a lower energy than the reference state, and it is known as a bound state. Positive energy terms indicate that the system has a higher energy than the reference state, and it is known as a free state.</p>

FAQ: The energy term in Schroedinger equation

What is the energy term in the Schroedinger equation?

The energy term in the Schroedinger equation is a mathematical representation of the total energy of a quantum mechanical system, including both its kinetic and potential energy components.

How is the energy term calculated in the Schroedinger equation?

The energy term is calculated by solving the Schroedinger equation, which is a differential equation that describes the behavior of quantum systems. The energy is one of the solutions to the equation, along with the wave function.

Why is the energy term important in the Schroedinger equation?

The energy term is important because it allows us to understand and predict the behavior of quantum systems. It helps us determine the allowed energy levels and the corresponding wave functions of a system.

How does the energy term affect the behavior of particles in a quantum system?

The energy term affects the behavior of particles in a quantum system by determining the probability of finding the particle in a particular energy state. The higher the energy, the lower the probability of finding the particle in that state.

Can the energy term be negative in the Schroedinger equation?

Yes, the energy term can be negative in the Schroedinger equation. This indicates that the system has a lower energy than the reference state, and it is known as a bound state. Positive energy terms indicate that the system has a higher energy than the reference state, and it is known as a free state.

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