Thermodynamics & PV work relationships

Nonetheless, it seems like they are struggling with understanding the relationships between ΔH, ΔU, q & W and constants P, V, and T. They mention some derivations and equations they understand, but are still feeling confused. They ask for a clear explanation of when Δ_ = 0 and hope that someone can provide some statements to help them get back on track.
  • #1
speny83
17
0
Hi all, studying for a physical chemistry exam tomorrow morning and I'm getting really confused. I am hoping somebody has an easy to understand explanation of How a lot of this stuff works.

specifically the relationships between ΔH, ΔU, q & W and constan P,V & T
i.e. if P is constant how these relate VS If T is constant.

I understand the derivations of Heat transfer for constant P=constant and V= constant; as well as Wrev and wirr

also, I know the ΔU=w+q and dH=dU+d(pv)...is this last one the trick to finding U and H for given process?


I guess i don't really have a question, just pumping so much stuff into my head its all spinning around in circles and hoping someone can provide a couple statements that get me back on track.

Maybe a good place to start is if you could clearly explain when/where/why Δ_=0 for some of the above, i think maybes that where i getting all mixed up.

As always I really appreciate you helpful folks on this forum! Thanks.
 
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  • #2
It isn't clear precisely what this OP is asking.
 

FAQ: Thermodynamics & PV work relationships

What is thermodynamics?

Thermodynamics is the branch of physics that deals with the relationship between heat, energy, and work.

What is PV work?

PV work is the work done by a gas as it expands or contracts at constant pressure (P) and volume (V).

What is the first law of thermodynamics?

The first law of thermodynamics states that energy cannot be created or destroyed, only transferred or converted from one form to another.

How does PV work relate to the first law of thermodynamics?

PV work is a form of energy transfer, and therefore, it is governed by the first law of thermodynamics. This means that the amount of work done by a gas is equal to the change in its internal energy plus the heat added to or removed from the system.

What is the formula for calculating PV work?

The formula for PV work is W = PΔV, where P is the constant pressure and ΔV is the change in volume.

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