Time-dependent to time-independent Schrödinger equation

In summary, separation of variables is a technique used to solve multivariable differential equations when one variable can be isolated on one side of the equation. It is possible to do this in the time-dependent Schrödinger equation when the potential does not depend on time. However, if the potential is time-dependent, this technique cannot be applied.
  • #1
LagrangeEuler
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Why you can do separation of variables in time-dependent

Schrödinger equation

[tex]i \hbar \frac{\partial \psi(\vec{r},t)}{\partial t}=-\frac{\hbar^2}{2m}\Delta \psi(\vec{r},t)+V(\vec{r})\psi(\vec{r},t)[/tex]
with
[tex]\psi(\vec{r},t)=\varphi(\vec{r})T(t)[/tex]
and when in general is that possible?
 
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  • #2
LagrangeEuler said:
and when in general is that possible?
When it works!
 
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  • #3
And when it works?
 
  • #4
The separability of time dependence is a simplifying assumption in the context of the explicit time independence of the potential. But a strict condition is valid in the opposite way: If the potential is time-dependent, the assumption of splitting (separation of) variables is untenable.
 
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  • #5
LagrangeEuler said:
And when it works?
Separation of variables is a general technique for solving multivariable differential equations, when we can algebraically manipulate the equation to get all of one variable on one side and all of the other variable on the other side.

The Schrodinger equation takes this form when the Hamiltonian is a function of position but not of time.
 
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  • #6
I think it would be better to later look into how the wave function can also be represented as a product of it's "spatial" part and "spin" part
This is a widely used method to simplify multivariable differential equations..
 
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FAQ: Time-dependent to time-independent Schrödinger equation

What is the Schrödinger equation?

The Schrödinger equation is a mathematical equation that describes how quantum systems, such as atoms and molecules, evolve over time. It was developed by Austrian physicist Erwin Schrödinger in 1926 and is a fundamental concept in quantum mechanics.

What is the difference between the time-dependent and time-independent Schrödinger equation?

The time-dependent Schrödinger equation describes the evolution of a quantum system over time, taking into account external forces and changes in energy. The time-independent Schrödinger equation, on the other hand, describes the stationary states of a system, where the energy remains constant.

What is the physical significance of the Schrödinger equation?

The Schrödinger equation is a fundamental equation in quantum mechanics and is used to calculate the probability of finding a particle in a particular state or location. It also helps to explain the wave-like behavior of particles at the quantum level.

What are the key assumptions of the Schrödinger equation?

The Schrödinger equation is based on several key assumptions, including the wave-particle duality of matter, the superposition principle, and the concept of quantization of energy. It also assumes that the system being studied is isolated and that all interactions can be described by a single wave function.

How is the Schrödinger equation used in practical applications?

The Schrödinger equation has many practical applications, including predicting the behavior of atoms and molecules in chemical reactions, understanding the properties of materials at the nanoscale, and developing quantum technologies such as quantum computing and cryptography.

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