Understanding Energy Eigenstates: Orbitals and Energy Bands Explained

In summary, energy eigenstates refer to states in a quantum system that have a defined and constant energy, and are commonly used to describe a variety of systems. The selection of a preferred basis depends on the context and can involve the energy eigenstates of the Hamiltonian for a Morse potential or the Hamiltonian describing the electrons and their interaction with the nucleus. This is known as environmental decoherence and can be influenced by various factors.
  • #1
lucas_
413
23
Does Energy Eigenstates refer to each orbital from the ground state or within one orbital in terms of the kinetic and potential energy of the electron in the orbital or from energy bands of molecular system? What is the term for each case called?
 
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  • #2
That would depend on what the state was describing. The electron will have a state and the molecule will have a different one. I guess they would be called the state of the electron and the state of the molecule.
 
  • #3
Energy eigenstate means that it is an eigenstate of the Hamiltonian, and therefore has a defined (constant) energy. It is a common expression for all sorts of quantum systems.
 
  • #4
DrClaude said:
Energy eigenstate means that it is an eigenstate of the Hamiltonian, and therefore has a defined (constant) energy. It is a common expression for all sorts of quantum systems.

Can you give an example of the most common applications for this. I'd like to know to if the state of the electron or the state of the molecule is the most common use.
 
  • #5
There is no "most common use," it is a matter of context. If you're talking about electronics states of an atom, then these are energy eigenstates of the Hamiltonian describing the electrons and their interaction with the nucleus. If you are talking about the vibrations of a diatomic molecule, then they can be as simplified as the energy eigenstates of the Hamiltonian for a Morse potential, without any consideration for electrons (Born-Oppenheimer approximation).

Basically, you have a Hamiltonian ##\hat{H}## describing some quantum system, so the ##\psi_i## such that
$$
\hat{H} \psi_i = E_i \psi_i
$$
are energy eigenstates. The physics being describe basically boil down to what is in ##\hat{H}##.

If this is still not clear, you will have to give a more explicit context for your question.
 
  • #6
DrClaude said:
There is no "most common use," it is a matter of context. If you're talking about electronics states of an atom, then these are energy eigenstates of the Hamiltonian describing the electrons and their interaction with the nucleus. If you are talking about the vibrations of a diatomic molecule, then they can be as simplified as the energy eigenstates of the Hamiltonian for a Morse potential, without any consideration for electrons (Born-Oppenheimer approximation).

Basically, you have a Hamiltonian ##\hat{H}## describing some quantum system, so the ##\psi_i## such that
$$
\hat{H} \psi_i = E_i \psi_i
$$
are energy eigenstates. The physics being describe basically boil down to what is in ##\hat{H}##.

If this is still not clear, you will have to give a more explicit context for your question.

In environmental decoherence.. in the selection of preferred basis in energy eigenstates (when position basis is not chosen or in addition to).. does it usually choose the energy eigenstates of the Hamiltonian for a Morse potential or the Hamiltonian describing the electrons and their interaction with the nucleus?
 

FAQ: Understanding Energy Eigenstates: Orbitals and Energy Bands Explained

What are energy eigenstates?

Energy eigenstates are the quantized energy levels that an electron can occupy in an atom or molecule. These states are described by the Schrödinger equation and are the basis for understanding the behavior of electrons in a system.

How are orbitals related to energy eigenstates?

Orbitals are the regions around an atom where an electron is most likely to be found. These regions are determined by the energy eigenstates and can be visualized as the "clouds" of electron density around an atom. Each orbital corresponds to a specific energy eigenstate.

What is the significance of energy bands?

Energy bands refer to the range of energy levels that electrons can occupy in a solid material. These bands are created by the overlapping of energy eigenstates from multiple atoms, and play a crucial role in determining the electrical and optical properties of materials.

How do energy eigenstates and orbitals differ from each other?

While both energy eigenstates and orbitals describe the behavior of electrons, they differ in their mathematical formulations and physical interpretations. Energy eigenstates are solutions to the Schrödinger equation and represent the quantized energy levels of electrons, while orbitals are probability distributions that describe the likelihood of finding an electron in a specific region around an atom.

Can you explain the concept of degeneracy in energy eigenstates?

Degeneracy refers to the situation where multiple energy eigenstates have the same energy level. This can occur when there are symmetries in a system that result in different quantum states having the same energy. Degeneracy has important implications in quantum mechanics and can affect the behavior of electrons in a system.

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