Vibrational frequencies of molecules

In summary, the vibrational frequency of D2 is half of the vibrational frequency of H2, assuming that the "spring constant" of attracting forces is the same for both species. This is because the reduced mass of two identical atoms is half of the mass of a single atom, and the frequency is inversely proportional to the square root of the mass. Therefore, the vibrational frequency of D2 is 6.1 × 1013 Hz.
  • #1
Bearbull24.5
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Homework Statement


The mass of the deuterium molecule D2 is twice that of the hydrogen molecule H2. If the vibrational frequency of H2 is 1.22 × 1014 Hz, what is the vibrational frequency of D2, assuming that the “spring constant” of attracting forces is the same for the two species?
Answer in units of Hz.


Homework Equations


Iowo=Ifwf
Io/f=(1/2)mr^2


The Attempt at a Solution



I want to use the above equation to solve this problem but I do not think that is the correct equation to use. There are too many variables that are not given in the question that I don't believe we are expected to know.
 
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  • #2
It is vibration, not rotation...

How is related the vibration frequency to the mass? ehild
 
  • #3
So it would be a simple harmonic motion problem?

v=(1/2*pi)(sqrt(k/m))?
 
  • #4
Yes, the only difference is that we have two vibrating particles instead of one. This is a two-body problem, which can be treated as a simple harmonic oscillator with the same spring constant, but with a "reduced mass" instead of m. The reciprocal of the reduced mass is the sum of the reciprocal of the individual masses. We have two identical atoms now, so the reduced mass is just half of that of a single atom.

ehild
 
  • #5
So for this problem I need to find out what the mass of a single atom is?
 
  • #6
Do I even need to know the values for the spring constant and masses?
 
  • #7
f=(1/2*pi)(sqrt(k/m)), so if m is doubled, what happens to f?
 

Related to Vibrational frequencies of molecules

What are vibrational frequencies of molecules?

Vibrational frequencies of molecules refer to the specific energy levels at which molecules vibrate. As molecules are made up of atoms bonded together, they can vibrate at different frequencies depending on the strength and type of bonds between the atoms.

How are vibrational frequencies measured?

Vibrational frequencies are measured using a technique called infrared spectroscopy. This involves passing infrared light through a sample of the molecule and measuring the amount of light absorbed. The absorbed energy corresponds to the vibrational frequency of the molecule.

What factors affect the vibrational frequencies of molecules?

The main factors that affect the vibrational frequencies of molecules are the masses of the atoms involved, the strength and type of bonds between the atoms, and the shape of the molecule. These factors influence how easily the atoms can vibrate and at what frequency.

Why are vibrational frequencies important in chemistry?

Vibrational frequencies are important in chemistry because they provide information about the structure and bonding of molecules. By analyzing the vibrational frequencies, scientists can identify the types of bonds present in a molecule and determine its molecular structure, which is crucial in understanding its properties and behavior.

How can vibrational frequencies be used in real-world applications?

Vibrational frequencies have a wide range of applications in various fields. In chemistry, they are used in the analysis and identification of chemical compounds. In medicine, they are used in infrared spectroscopy to diagnose diseases. They are also used in industries such as food and pharmaceuticals to ensure the quality and purity of products.

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