Volume of Balloon at 23K and 299K

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To determine the volume of a balloon containing 9.9 g of liquid helium at 1.00 atm pressure, the ideal gas law (PV=nRT) is applied. The conversion of helium mass to moles yields approximately 2.473 moles. Calculating the volume at 23.0 K results in approximately 472.95 liters, while at 299 K, the volume is around 6148.31 liters. However, the calculations are incorrect due to the use of pressure in atmospheres instead of pascals, which is necessary for consistency with SI units. Correcting the pressure unit will provide accurate volume results in cubic meters, which can then be converted to liters.
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Homework Statement



Imagine that 9.9 g of liquid helium, initially at 4.20 K, evaporate into an empty balloon that is kept at 1.00-atm pressure. What is the volume of the ballonat the following?

(a) 23.0 K(b) 299 K

Homework Equations



PV=nRT

The Attempt at a Solution



I converted th 9.9g of Helium to number of moles. n=2.473mol
and used that to find the volume at T=23 and T=299, but it isn't right.

steps
1) n=9.9g=(9.9g/(4.003g/mol))=2.47314 mol
R=8.314472 <-- gas constant
P= 1 as stated in the problem

V@ T=23 : V=(nRT)/P -> (2.47314*8.314472*23)/1 --> V=472.9466 L

V@ T=299 : V=(nRT)/P -> (2.47314*8.314472*299)/1 --> V=6148.30591237 L
I'm guessing I need to do something with T=4.2 first, but I'm not sure what.
 
Last edited:
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Please show your work, i.e. exactly what you did, and then perhaps we can determine where you went wrong.
 
edited to show work
 
Your problem is a mixed bag of units. When you write pV = nRT
p is measured in Pa (or N/m2) not atmospheres. How many Pa is one atmosphere? Your textbook should have the number. When you put in the correct pressure, the answer should come out in m3. If you want liters you need to make another conversion.
 
The book claims the answer is that all the magnitudes are the same because "the gravitational force on the penguin is the same". I'm having trouble understanding this. I thought the buoyant force was equal to the weight of the fluid displaced. Weight depends on mass which depends on density. Therefore, due to the differing densities the buoyant force will be different in each case? Is this incorrect?

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