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Thadis
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I think I actually have solved it. I was right with the PV=nkT, I believe I previously messed up with the algebra.
Using the same meathod as in the text, calculate the entropy of mixing for a system of two monatomic ideal gases, A and B, whose relative proportion is arbitrary. Let N be the total number of molecules and let x be the fraction of these that are species B. You should find that
ΔS=-Nk[xlnx+(1-x)ln(1-x)]
Check that this expression reduces to the one given in the text when x= 1/2.
That S=Nk[ln(V(a/3n)^(3/2))+3/2] where a is just a whole bunch of stuff that I believe is irrelevant to the problem.
PV=nkT might be useful
also the fact that ln(x/y)=ln(x)-ln(y)
I know that the change of entropy will just be S_final-S_original but I do not know what really changes between the final and the original situations. Do I have to use the Ideal Gas law find out how big the volume would be?
Homework Statement
Using the same meathod as in the text, calculate the entropy of mixing for a system of two monatomic ideal gases, A and B, whose relative proportion is arbitrary. Let N be the total number of molecules and let x be the fraction of these that are species B. You should find that
ΔS=-Nk[xlnx+(1-x)ln(1-x)]
Check that this expression reduces to the one given in the text when x= 1/2.
Homework Equations
That S=Nk[ln(V(a/3n)^(3/2))+3/2] where a is just a whole bunch of stuff that I believe is irrelevant to the problem.
PV=nkT might be useful
also the fact that ln(x/y)=ln(x)-ln(y)
The Attempt at a Solution
I know that the change of entropy will just be S_final-S_original but I do not know what really changes between the final and the original situations. Do I have to use the Ideal Gas law find out how big the volume would be?
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