- #1
Morten
- 10
- 0
In the chapter 9-5 "The Linear Variation Method" p. 363 from the book: Basic Principles and Techniques of Molecular Quantum Mechanics by Ralph Christoffersen, the first thing he does is to minimize the energy, E = c†Hc/c†Sc, by requiring its derivative with respect to the coefficient cp* to equal zero. He claims the following expression:
dE/dcp* (c†Sc) + E d/dcp* (c†Sc) = d/dcp* (c†Hc) , whereas, by the quotient rule, I would claim:
((dE/dcp*)(c†Hc)(c†Sc) - (c†Hc) dE/dcp*(c†Sc)) / (c†Sc)2 = 0 , am I perhaps wrong?
dE/dcp* (c†Sc) + E d/dcp* (c†Sc) = d/dcp* (c†Hc) , whereas, by the quotient rule, I would claim:
((dE/dcp*)(c†Hc)(c†Sc) - (c†Hc) dE/dcp*(c†Sc)) / (c†Sc)2 = 0 , am I perhaps wrong?